Publication: Hetero-Octanuclear Cubane-Like and One-Dimensional Cyano Complexes with the N,N-Dimethylethylenediamine Ligand
| dc.authorscopusid | 49863490200 | |
| dc.authorscopusid | 16403949600 | |
| dc.authorscopusid | 36905553700 | |
| dc.authorscopusid | 36039473500 | |
| dc.contributor.author | Kürkçüoǧlu, G.S. | |
| dc.contributor.author | Yeşilel, O.Z. | |
| dc.contributor.author | Aksel, M. | |
| dc.contributor.author | Büyuk̈güngör, O. | |
| dc.date.accessioned | 2020-06-21T13:51:02Z | |
| dc.date.available | 2020-06-21T13:51:02Z | |
| dc.date.issued | 2015 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Kürkçüoǧlu] Güneş Süheyla, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Aksel] Mehran, Department of Biophysics, Aydin Adnan Menderes University, Aydin, Efeler, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey | en_US |
| dc.description.abstract | A series of complexes containing dmen (dmen = N,N-dimethylethylenediamine) units and cyano groups, namely bimetallic octanuclear and binuclear [Zn<inf>4</inf>(dmen)<inf>8</inf>Ni<inf>4</inf>(CN)<inf>16</inf>] (1), [Cd<inf>4</inf>(dmen)<inf>8</inf>Ni<inf>4</inf>(CN)<inf>16</inf>] (2), [Zn(dmen)<inf>2</inf>Pd(μ-CN)<inf>2</inf>(CN)<inf>2</inf>] (3) and [Cd(dmen)<inf>2</inf>Pd(μ-CN)<inf>2</inf>(CN)<inf>2</inf>] (4), have been synthesized and characterized by elemental, spectral (FT-IR and Raman) and thermal analyses techniques. The molecular structures of the complexes have been determined by the single crystal X-ray diffraction technique. The X-ray analyses of 1 and 2 show heterometallic octanuclear cubane-like structures in which Zn(II) or Cd(II) and Ni(II) ions reside in alternate corners, whereas complexes 3 and 4 display one-dimensional chain structures. © 2014 Elsevier Ltd. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/j.poly.2014.09.019 | |
| dc.identifier.endpage | 726 | en_US |
| dc.identifier.issn | 0277-5387 | |
| dc.identifier.scopus | 2-s2.0-84908373943 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 720 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.poly.2014.09.019 | |
| dc.identifier.volume | 85 | en_US |
| dc.identifier.wos | WOS:000347582900091 | |
| dc.identifier.wosquality | Q2 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Ltd | en_US |
| dc.relation.ispartof | Polyhedron | en_US |
| dc.relation.journal | Polyhedron | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Cubane-Like Complexes | en_US |
| dc.subject | Hetero-Octanuclear Complexes | en_US |
| dc.subject | N,N-Dimethylethylenediamine Complexes | en_US |
| dc.subject | Tetracyanonickelate Complexes | en_US |
| dc.subject | Tetracyanopalladate Complexes | en_US |
| dc.title | Hetero-Octanuclear Cubane-Like and One-Dimensional Cyano Complexes with the N,N-Dimethylethylenediamine Ligand | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |