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Crystal Structure and Physico-Chemical Properties of Diaquabis(1,10-Phenanthroline)manganese(II) Disaccharinate Monohydrate

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dc.authorscopusid58717985000
dc.authorscopusid55394789700
dc.authorscopusid6603007969
dc.authorscopusid6603822664
dc.authorscopusid15722124000
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorYilmaz, F.
dc.contributor.authorTopcu, Y.
dc.contributor.authorAndaç, O.
dc.contributor.authorGöven, K.
dc.date.accessioned2020-06-21T15:49:25Z
dc.date.available2020-06-21T15:49:25Z
dc.date.issued2001
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yilmaz] Fatih, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Topcu] Yildiray, Institute of Chemistry, Ss. Cyril and Methodius University in Skopje, Skopje, North Macedonia; [Andaç] Ömer, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Göven] K., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractA novel manganese complex, [Mn(phen)<inf>2</inf>(H<inf>2</inf>O)<inf>2</inf>](sac)<inf>2</inf>· H<inf>2</inf>O, was synthesized by the reaction of [Mn(sac)<inf>2</inf>(H<inf>2</inf>O)<inf>4</inf>]·2H<inf>2</inf>O with 1,10-phenantroline in aqueous solution and characterized by elemental analysis, IR spectral evidence, magnetic measurements, thermal analysis and single crystal X-ray diffraction. The compound crystallizes in triclinic system, space group P-1, with Z = 2. The saccharinate ions do not coordinate the central metal, instead are present as the complementary anions. In the complex cation, Mn(II) is coordinated by two phen and two aqua ligands, and exhibits a distorted octahedral coordination with a high-spin configuration. The presence of lattice and coordinate water molecules are also confirmed by thermal analysis and IR spectroscopy. © 2001 Elsevier Science B.V.en_US
dc.identifier.doi10.1016/S0022-2860(00)00730-4
dc.identifier.endpage13en_US
dc.identifier.issn0022-2860
dc.identifier.scopus2-s2.0-0035966529
dc.identifier.scopusqualityQ1
dc.identifier.startpage9en_US
dc.identifier.urihttps://doi.org/10.1016/S0022-2860(00)00730-4
dc.identifier.volume560en_US
dc.identifier.wosWOS:000167079800002
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Science BVen_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.journalJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject1,10-Phenantroline Complexesen_US
dc.subjectCrystal Structureen_US
dc.subjectMn(II) Complexesen_US
dc.subjectSaccharinatesen_US
dc.subjectSpectraen_US
dc.subjectThermal Analysisen_US
dc.titleCrystal Structure and Physico-Chemical Properties of Diaquabis(1,10-Phenanthroline)manganese(II) Disaccharinate Monohydrateen_US
dc.typeArticleen_US
dspace.entity.typePublication

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