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EPR Study of VO2+ Doped Diammonium Tricadmium Tetrakis (Sulfate) Pentahydrate [(NH4)2Cd3(SO4)4·5H2O] Single Crystals

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dc.authorscopusid57522079200
dc.authorscopusid6603897211
dc.authorscopusid16068224200
dc.contributor.authorKartal, I.
dc.contributor.authorKarabulut, B.
dc.contributor.authorBozkurt, E.
dc.date.accessioned2020-06-21T14:49:02Z
dc.date.available2020-06-21T14:49:02Z
dc.date.issued2010
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kartal] Ibrahim, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Karabulut] Bünyamin, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Bozkurt] Esat, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractElectron paramagnetic resonance (EPR) studies are carried out on vanadyl (VO2+) ions in diammonium tricadmium tetrakis (sulfate) pentahydrate single crystals at room temperature. The EPR spectra of a single crystal exhibit resonance signals characteristic to VO2+ ions. The analysis of EPR spectra indicates that the VO2+ ions in single crystals show two magnetically inequivalent VO2+ sites in distinct orientations occupying substitutional positions in the lattice and showing very high angular dependence. They form in octahedral coordination with tetragonal compression with C<inf>4v</inf> symmetry. The spin Hamiltonian parameters are determined, and these parameters have been used to estimate the bonding coefficients of the VO2+ ion in a diammonium tricadmium tetrakis (sulfate) pentahydrate lattice. The parallel and perpendicular components of axially symmetric g and hyperfine (A) tensors are evaluated and the results are discussed and compared with previous reports. © 2010 Verlag der Zeitschrift für Naturforschung, Tübingen.en_US
dc.identifier.doi10.1515/zna-2010-0412
dc.identifier.endpage352en_US
dc.identifier.issn0932-0784
dc.identifier.issn1865-7109
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-77954007346
dc.identifier.scopusqualityQ3
dc.identifier.startpage347en_US
dc.identifier.urihttps://doi.org/10.1515/zna-2010-0412
dc.identifier.volume65en_US
dc.identifier.wosWOS:000278748800012
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherVerlag der Zeitschrift fur Naturforschungen_US
dc.relation.ispartofZeitschrift Für Naturforschung Section A-A Journal of Physical Sciencesen_US
dc.relation.journalZeitschrift Fur Naturforschung Section A-A Journal of Physical Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectEPRen_US
dc.subjectESRen_US
dc.subjectSingle Crystalen_US
dc.subjectVanadyl Ionen_US
dc.titleEPR Study of VO2+ Doped Diammonium Tricadmium Tetrakis (Sulfate) Pentahydrate [(NH4)2Cd3(SO4)4·5H2O] Single Crystalsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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