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Structural, Spectroscopic Characterization and EPR Spectra of Nitrato-μ Cu(II)Ag Complex

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dc.authorscopusid15137652400
dc.authorscopusid55259960900
dc.authorscopusid8405708700
dc.authorscopusid16068224200
dc.authorscopusid36039473500
dc.contributor.authorŞenyüz, N.
dc.contributor.authorYılmaz, B.
dc.contributor.authorBati, H.
dc.contributor.authorBozkurt, E.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T14:16:29Z
dc.date.available2020-06-21T14:16:29Z
dc.date.issued2013
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Şenyüz] Nuray, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yılmaz] Betül, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Bati] Hümeyra, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Bozkurt] Esat, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractA novel heterodinuclear complex formed by the reaction of silver nitrate with Schiff base complex of copper(II) has been synthesized and characterized by Infrared (IR), ultraviolet-visible (UV-VIS), electron paramagnetic resonance (EPR) and X-ray diffraction methods. Preparation and crystal structure of the heterodinuclear complex, LCuAgNO<inf>3</inf>, (L = N,N′-ethylenebis(3- methoxysalicylideneimine) are reported. The crystal structure consists of ordered dinuclear units with CuII and AgI ions are bridged by two oxygen atoms of Schiff base ligand. The copper(II) ion has a distorted square-planar geometry involving the N<inf>2</inf>O<inf>2</inf> donor set of Schiff base ligand. The g-values were calculated for title complex both in polycrystalline state at 298 K and in frozen DMF (113 K). The evaluated metal-ligand bonding parameters showed strong in-plane σ bonding. © 2012 Published by Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.saa.2012.09.063
dc.identifier.endpage171en_US
dc.identifier.issn1386-1425
dc.identifier.pmid23099175
dc.identifier.scopus2-s2.0-84867746204
dc.identifier.scopusqualityQ1
dc.identifier.startpage167en_US
dc.identifier.urihttps://doi.org/10.1016/j.saa.2012.09.063
dc.identifier.volume101en_US
dc.identifier.wosWOS:000312690800025
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopyen_US
dc.relation.journalSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrystal Structureen_US
dc.subjectEPRen_US
dc.subjectIRen_US
dc.subjectUVen_US
dc.subjectX-Ray Diffractionen_US
dc.titleStructural, Spectroscopic Characterization and EPR Spectra of Nitrato-μ Cu(II)Ag Complexen_US
dc.typeArticleen_US
dspace.entity.typePublication

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