Publication: One-Dimensional Coordination Polymers of Co(II) and Cd(II)-Squarate with 2-Methylimidazole and 4(5)-Methylimidazole Ligands
| dc.authorscopusid | 25640606900 | |
| dc.authorscopusid | 16403949600 | |
| dc.authorscopusid | 36039473500 | |
| dc.contributor.author | Erer, H. | |
| dc.contributor.author | Yeşilel, O.Z. | |
| dc.contributor.author | Büyuk̈güngör, O. | |
| dc.date.accessioned | 2020-06-21T14:52:38Z | |
| dc.date.available | 2020-06-21T14:52:38Z | |
| dc.date.issued | 2010 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Erer] Hakan, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey | en_US |
| dc.description.abstract | Two new mixed-ligand coordination polymers, {[Co(μ<inf>1,3</inf>-sq)(H<inf>2</inf>O)<inf>2</inf>(2-Meim)<inf>2</inf>]·2(2-Meim)}<inf>n</inf> (1) and [Cd(μ<inf>1,3</inf>-sq)(H<inf>2</inf>O)<inf>2</inf>(4(5)-Meim)<inf>2</inf>]<inf>n</inf> (2), (sq = squarate, 2-Meim = 2-methylimidazole, 4(5)-Meim = 5-methylimidazole) have been synthesized and structurally characterized by X-ray crystallography. The spectral (IR and UV-Vis) and thermal analyses are also reported. The Co(II) and Cd(II) ions are distorted octahedrally coordinated by four oxygen atoms of two O1-O3-bridging squarate ligands and two trans-aqua ligands, and by two nitrogen atoms of the trans-imidazole (2-Meim or 4(5)-Meim) ligands. The structures of 1 and 2 consist of one-dimensional chains of μ-1,3-squarato bridged metal(II) complex units. These chains are held together by hydrogen bonding interactions, forming three-dimensional framework. © 2009 Elsevier Ltd. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/j.poly.2009.12.017 | |
| dc.identifier.endpage | 1167 | en_US |
| dc.identifier.issn | 0277-5387 | |
| dc.identifier.issue | 3 | en_US |
| dc.identifier.scopus | 2-s2.0-75149141313 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 1163 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.poly.2009.12.017 | |
| dc.identifier.volume | 29 | en_US |
| dc.identifier.wos | WOS:000275640700032 | |
| dc.identifier.wosquality | Q2 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Ltd | en_US |
| dc.relation.ispartof | Polyhedron | en_US |
| dc.relation.journal | Polyhedron | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Coordination Polymers | en_US |
| dc.subject | Methylimidazole Complexes | en_US |
| dc.subject | Polynuclear Complexes | en_US |
| dc.subject | Squarate Complexes | en_US |
| dc.subject | Supramolecular Complexes | en_US |
| dc.title | One-Dimensional Coordination Polymers of Co(II) and Cd(II)-Squarate with 2-Methylimidazole and 4(5)-Methylimidazole Ligands | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |