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A Disparate 3-D Silver(I) Coordination Polymer of Pyridine-3,5 and Pyrimidine with Strong Intermetallic Interactions: X-Ray Crystallography, Photoluminescence and Antimicrobial Activity

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dc.authorscopusid6603157555
dc.authorscopusid28067744200
dc.authorscopusid26429877700
dc.authorscopusid36039473500
dc.contributor.authorHamamci, S.H.
dc.contributor.authorDemir, S.
dc.contributor.authorSariboǧa, B.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T13:51:50Z
dc.date.available2020-06-21T13:51:50Z
dc.date.issued2015
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Hamamci] Sevim, Department of Materials Science and Engineering, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Demir] Serkan, Department of Chemistry, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Sariboǧa] Bahtiyar, School of Health, Sinop Üniversitesi, Sinop, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractA polymeric silver(I) complex, [Ag<inf>4</inf>(-pydc)<inf>2</inf>(-pm)<inf>2</inf>]<inf>n</inf> (1) (pydc = pyridine-3,5-dicarboxylate and pm = pyrimidine), has been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis, and single-crystal X-ray diffraction. X-ray crystallographic data of 1 revealed that pydc exhibits two different coordinaton modes that play a key role in the construction of the 3-D crystal network including Ag-carboxylate clusters in which close Ag-Ag distances exist. The magnitudes of close Ag-Ag interactions in second-order energy (E2) have been revealed by natural bond orbital analysis performed with single point energy calculation using the experimental geometry of 1. Furthermore, the luminescent properties of 1 show strong fluorescence with two emission maxima in the visible region. Also, 1 has antifungal activity on Candida albicans (MIC value, 4 g mL-1) and good antibacterial activity on micro-organisms (MIC value, 64-256 g mL-1). © 2014 Taylor & Francis.en_US
dc.identifier.doi10.1080/00958972.2014.978307
dc.identifier.endpage168en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-84941733247
dc.identifier.scopusqualityQ3
dc.identifier.startpage155en_US
dc.identifier.urihttps://doi.org/10.1080/00958972.2014.978307
dc.identifier.volume68en_US
dc.identifier.wosWOS:000346266500012
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherTaylor and Francis Ltd. michael.wagreich@univie.ac.aten_US
dc.relation.ispartofJournal of Coordination Chemistryen_US
dc.relation.journalJournal of Coordination Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAntimicrobial Propertiesen_US
dc.subjectCoordination Polymeren_US
dc.subjectPhotoluminescent Propertiesen_US
dc.subjectPyridine-3,5-Dicarboxylateen_US
dc.subjectSilver(I) Complexen_US
dc.titleA Disparate 3-D Silver(I) Coordination Polymer of Pyridine-3,5 and Pyrimidine with Strong Intermetallic Interactions: X-Ray Crystallography, Photoluminescence and Antimicrobial Activityen_US
dc.typeArticleen_US
dspace.entity.typePublication

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