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Electrochemical, Spectroscopic and Computational Studies on Complexation of Oxacillin With Cu(II) and Co(II) Ions. Synthesis and Ligand Hydrolysis

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dc.authorscopusid7004269359
dc.authorscopusid57196047139
dc.authorscopusid7003883041
dc.authorscopusid6603524165
dc.contributor.authorÇoşkun, E.
dc.contributor.authorDuman, E.
dc.contributor.authorAcar-Selcuki, N.
dc.contributor.authorBi̇Çer, E.
dc.date.accessioned2020-06-21T13:18:06Z
dc.date.available2020-06-21T13:18:06Z
dc.date.issued2017
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Çoşkun] Emine, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Duman] Emel, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Acar-Selcuki] Nursel S., Department of Chemistry, Ege Üniversitesi, Izmir, Turkey; [Bi̇Çer] Ender, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractIn this study, the synthesis and characterization of the complexes of oxacillin with Cu(II) and Co(II) ions are presented. These complexes were characterized by FT-IR spectroscopy and elemental analysis. The complexation process of Cu(II) and Co(II) ions with oxacillin in aqueous medium (Britton-Robinson buffer pH 7.4) was followed by means of square-wave voltammetry. Spectroscopic and elemental analysis results showed that Co(II) and Cu(II) complexes were formed with hydrolysed oxacillin anions. In addition, their stability constants and stoichiometric ratios were determined from voltammetric data. Computational results are in agreement with the experimental findings. © 2017 The Authors.en_US
dc.identifier.doi10.20964/2017.10.43
dc.identifier.endpage9377en_US
dc.identifier.issn1452-3981
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-85031327693
dc.identifier.scopusqualityQ3
dc.identifier.startpage9364en_US
dc.identifier.urihttps://doi.org/10.20964/2017.10.43
dc.identifier.volume12en_US
dc.identifier.wosWOS:000414422900044
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherElectrochemical Science Group mantonijevic@tf.bor.ac.yuen_US
dc.relation.ispartofInternational Journal of Electrochemical Scienceen_US
dc.relation.journalInternational Journal of Electrochemical Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectDensity Functional Theoryen_US
dc.subjectHydrolysisen_US
dc.subjectInfrared Spectroscopyen_US
dc.subjectOxacillin - Metal Ion Complexesen_US
dc.subjectSquare-Wave Voltammetryen_US
dc.titleElectrochemical, Spectroscopic and Computational Studies on Complexation of Oxacillin With Cu(II) and Co(II) Ions. Synthesis and Ligand Hydrolysisen_US
dc.typeArticleen_US
dspace.entity.typePublication

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