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Brorno(eta(4)-cycloocta-1,5-diene)[1-(2,3,4,5,6-pentafluorobenzyl)-3-(2, 4,6-trimethylbenzyl)benzimidazol-2-ylidenel rhodium(I)

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dc.authorscopusid56054780100
dc.authorscopusid8398877200
dc.authorscopusid14015553600
dc.authorscopusid7006471258
dc.authorscopusid36039473500
dc.contributor.authorDinçer, M.
dc.contributor.authorÖzdemir, Nutullah
dc.contributor.authorGülcemal, S.
dc.contributor.authorÇetinkaya, B.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T15:28:38Z
dc.date.available2020-06-21T15:28:38Z
dc.date.issued2006
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Dinçer] Muharrem, Department of Physics, Arts and Sciences Faculty, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Özdemir] Namık, Department of Physics, Arts and Sciences Faculty, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Gülcemal] S., Department of Chemistry, Ege Üniversitesi, Izmir, Turkey; [Çetinkaya] Bekir, Department of Chemistry, Ege Üniversitesi, Izmir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Arts and Sciences Faculty, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe title complex, [RhBr(C<inf>8</inf>H<inf>12</inf>)(C<inf>24</inf>H <inf>19</inf>F<inf>5</inf>N<inf>2</inf>)], has a distorted pseudo-square-planar geometry. The Rh - C bond distance between the N-heterocyclic ligand and the metal atom is 2.022(3). The angle between the carbene heterocycle and the coordination plane is 75.60(11)°. It is shown that the average Rh - C(cyclooctadiene) distance is linearly dependent on the Rh - C(imidazole) distance in this type of compound. The crystal structure contains one intramolecular and two intermolecular types of C - H⋯F interactions, as well as one type of π-π stacking interaction. © 2006 International Union of Crystallography.en_US
dc.identifier.doi10.1107/S0108270106016052
dc.identifier.endpagem254en_US
dc.identifier.issn0108-2701
dc.identifier.issn1600-5759
dc.identifier.issue6en_US
dc.identifier.pmid16763305
dc.identifier.scopus2-s2.0-33745136445
dc.identifier.startpagem252en_US
dc.identifier.urihttps://doi.org/10.1107/S0108270106016052
dc.identifier.volume62en_US
dc.identifier.wosWOS:000238686700015
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section C: Crystal Structure Communicationsen_US
dc.relation.journalActa Crystallographica Section C-Structural Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleBrorno(eta(4)-cycloocta-1,5-diene)[1-(2,3,4,5,6-pentafluorobenzyl)-3-(2, 4,6-trimethylbenzyl)benzimidazol-2-ylidenel rhodium(I)en_US
dc.typeArticleen_US
dspace.entity.typePublication

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