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A Highly Novel Dinickel Complex: A Hydrogen-Bonded Anti-Skew Carboxylate Bridge and a 2D Supramolecular Structure

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dc.authorscopusid35176279000
dc.authorscopusid27169186200
dc.authorscopusid7007181781
dc.authorscopusid56249121800
dc.authorscopusid6602965787
dc.authorscopusid36039473500
dc.contributor.authorKorkmaz, N.
dc.contributor.authorGökçe, A.G.
dc.contributor.authorAstley, S.T.
dc.contributor.authorAygün, M.
dc.contributor.authorAstley, D.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T14:53:50Z
dc.date.available2020-06-21T14:53:50Z
dc.date.issued2009
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Korkmaz] Neslihan, Department of Chemistry, Ege Üniversitesi, Izmir, Turkey; [Gökçe] Aytaç Gürhan, Department of Physics, Dokuz Eylül Üniversitesi, Izmir, Turkey; [Astley] Stephen Thomas, Department of Chemistry, Ege Üniversitesi, Izmir, Turkey; [Aygün] Muhittin, Department of Physics, Dokuz Eylül Üniversitesi, Izmir, Turkey; [Astley] Demet K., Department of Chemistry, Ege Üniversitesi, Izmir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractReaction of the tridentate Schiff base ligands obtained from 2,4-dihydroxybenzaldehyde and either l-isoleucine or l-tert-leucine with Ni(NO<inf>3</inf>)<inf>2</inf> in methanol/water solution in the presence of base afforded dinickel complexes. The crystal structure of the product derived from l-tert-leucine has been determined by X-ray crystallography. The octahedrally coordinated two Ni centers were found to be bridged by a single carboxylate group in an extremely unusual non-planar fashion. A 2D supramolecular structure, constructed by infinite hydrogen-bonded complex sheets parallel to the ab-plane of the unit cell, arises from intermolecular O-H⋯O hydrogen bonds. © 2009 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.inoche.2009.09.021
dc.identifier.endpage1208en_US
dc.identifier.issn1387-7003
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-70449704018
dc.identifier.scopusqualityQ2
dc.identifier.startpage1204en_US
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2009.09.021
dc.identifier.volume12en_US
dc.identifier.wosWOS:000272570500010
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherElsevier Science BVen_US
dc.relation.ispartofInorganic Chemistry Communicationsen_US
dc.relation.journalInorganic Chemistry Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBridging Carboxylateen_US
dc.subjectDinickel Complexesen_US
dc.subjectSupramolecular Structureen_US
dc.subjectTridentate Schiff Baseen_US
dc.titleA Highly Novel Dinickel Complex: A Hydrogen-Bonded Anti-Skew Carboxylate Bridge and a 2D Supramolecular Structureen_US
dc.typeArticleen_US
dspace.entity.typePublication

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