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Hetero-Metallic Coordination Polymers: Syntheses, Vibrational Spectra, Thermal Analyses and Crystal Structures of Trans-[M(n 2Ni(μ-CN) 4] N (M=Cu Zn(II) and Cd(II))

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dc.authorscopusid49863490200
dc.authorscopusid16403949600
dc.authorscopusid25521868500
dc.authorscopusid36039473500
dc.contributor.authorKürkçüoǧlu, G.S.
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorKavlak, I.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T14:53:51Z
dc.date.available2020-06-21T14:53:51Z
dc.date.issued2009
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kürkçüoǧlu] Güneş Süheyla, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Kavlak] İlkan, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractThree cyano bridged hetero-metallic complexes of general formula, trans-[M(N-Meim) <inf>2</inf>Ni(μ-CN) <inf>4</inf>] <inf>n</inf> (N-Meim=N-methylimidazole and M=Cu(II), Zn(II) or Cd(II)) have been synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction, thermal analyses and elemental analyses. The crystallographic analyses reveal that the complexes, [Cu(N-Meim) <inf>2</inf>Ni(μ-CN) <inf>4</inf>] <inf>n</inf> (1), [Zn(N-Meim) <inf>2</inf>Ni(μ-CN) <inf>4</inf>] <inf>n</inf> (2) and [Cd(N-Meim) <inf>2</inf>Ni(μ-CN) <inf>4</inf>] <inf>n</inf> (3), have polymeric 2D networks. In the complexes, four cyanide groups of [Ni(CN) <inf>4</inf>] 2- coordinated to the adjacent M(II) ions and distorted octahedral geometries of complexes are completed by two nitrogen atoms of trans N-Meim ligands. Vibration assignments are given for all the observed bands and the spectral features also supported to the crystal structures of polynuclear complexes. © Springer Science+Business Media, LLC 2009.en_US
dc.identifier.doi10.1007/s10904-009-9295-3
dc.identifier.endpage548en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-77349115936
dc.identifier.scopusqualityQ1
dc.identifier.startpage539en_US
dc.identifier.urihttps://doi.org/10.1007/s10904-009-9295-3
dc.identifier.volume19en_US
dc.identifier.wosWOS:000272035600014
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.journalJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCyano-Bridged Complexesen_US
dc.subjectHetero-Metallic Complexesen_US
dc.subjectN-Methylimidazole Complexesen_US
dc.subjectTetracyanonickelate(II) Complexesen_US
dc.titleHetero-Metallic Coordination Polymers: Syntheses, Vibrational Spectra, Thermal Analyses and Crystal Structures of Trans-[M(n 2Ni(μ-CN) 4] N (M=Cu Zn(II) and Cd(II))en_US
dc.typeArticleen_US
dspace.entity.typePublication

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