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Synthesis and Structural Characterization of a New Schiff Base Macrocyclic Ligand Containing a Piperazine Head Unit and Its Metal Complexes. Crystal Structure of the Co(II) Complex

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dc.authorscopusid26643429400
dc.authorscopusid35330900300
dc.authorscopusid23569766000
dc.authorscopusid35329201400
dc.authorscopusid56350482600
dc.authorscopusid7004682640
dc.authorscopusid35570284800
dc.contributor.authorKeypour, H.
dc.contributor.authorRahpeyma, N.
dc.contributor.authorRezaeivala, M.
dc.contributor.authorArzhangi, P.
dc.contributor.authorBayat, M.
dc.contributor.authorValencia, L.
dc.contributor.authorElerman, Y.
dc.date.accessioned2020-06-21T14:06:13Z
dc.date.available2020-06-21T14:06:13Z
dc.date.issued2013
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Keypour] Hassan, Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Hamedan, Iran; [Rahpeyma] Nasibeh, Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Hamedan, Iran; [Rezaeivala] Majid, Department of Chemical Engineering, Hamedan University of Technology, Hamadan, Iran; [Arzhangi] Parisa, Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Hamedan, Iran; [Bayat] Mehdi, Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Hamedan, Iran; [Valencia] Laura, Department of Inorganic Chemistry, Universidade de Vigo, Vigo, Galicia, Spain; [Elerman] Yalci̧in, Department of Engineering Physics, University of Ankarac, Besevler, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractA new macrocyclic Schiff base ligand, L, was synthesized by the condensation reaction of 1,4-bis(2-formylphenyl)piperazine and 1,4-diaminobutane in acetonitrile. The Schiff base ligand was characterized by elemental analysis, IR and mass spectroscopy. Three new Co(II), Cu(II) and Zn(II) complexes, [CoL(NO<inf>3</inf>)]ClO<inf>4</inf>, [CuL(NO<inf>3</inf>)]ClO <inf>4</inf> and [ZnL(NO<inf>3</inf>)]ClO<inf>4</inf>, were prepared and characterized by elemental analyses, IR, FAB-MS, conductivity measurements and in the case of [ZnL(NO<inf>3</inf>)]ClO<inf>4</inf> by 1H NMR spectroscopy. The X-ray crystal structure of [CoL(NO<inf>3</inf>)]ClO <inf>4</inf> showed that the complex contains Co(II) in a distorted octahedral geometry with an N<inf>4</inf>O<inf>2</inf> core. Also, theoretical studies on the interaction of the nitrate ion and metal ions were carried out. © 2012 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.poly.2012.12.020
dc.identifier.endpage122en_US
dc.identifier.issn0277-5387
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-84874330376
dc.identifier.scopusqualityQ2
dc.identifier.startpage117en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2012.12.020
dc.identifier.volume51en_US
dc.identifier.wosWOS:000318958700016
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.journalPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCo(II), Cu(II) and Zn(II) Complexesen_US
dc.subjectMacrocyclic Schiff Baseen_US
dc.subjectPiperazineen_US
dc.subjectTheoretical Studyen_US
dc.subjectX-Ray Crystal Structureen_US
dc.titleSynthesis and Structural Characterization of a New Schiff Base Macrocyclic Ligand Containing a Piperazine Head Unit and Its Metal Complexes. Crystal Structure of the Co(II) Complexen_US
dc.typeArticleen_US
dspace.entity.typePublication

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