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Thermokinetic and TG/DSC-FTIR Study of Pea Waste Biomass Pyrolysis

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dc.contributor.authorMusellim, Ece
dc.contributor.authorTahir, Mudassir Hussain
dc.contributor.authorAhmad, Muhammad Sajjad
dc.contributor.authorCeylan, Selim
dc.date.accessioned2020-06-21T13:11:00Z
dc.date.available2020-06-21T13:11:00Z
dc.date.issued2018
dc.departmentOMÜen_US
dc.department-temp[Musellim, Ece -- Ceylan, Selim] Ondokuz Mayis Univ, Fac Engn, Dept Chem Engn, TR-55139 Kurupelit, Samsun, Turkey -- [Tahir, Mudassir Hussain] Univ Sci & Technol, Dept Polymer Sci & Engn, Hefei 230026, Anhui, Peoples R China -- [Ahmad, Muhammad Sajjad] Govt Coll Univ Faisalabad, Dept Bioinformat & Biotechnol, Bioenergy Res Ctr, Faisalabad 38000, Pakistan -- [Ahmad, Muhammad Sajjad] Univ Waterloo, Dept Chem Engn, Waterloo, ON, Canada --en_US
dc.description.abstractIn this study agricultural waste biomass pea residue was investigated for its potential to be used in pyrolysis for production of bioenergy. Experiments were carried out in a TG/DSC-FTIR under an inert nitrogen medium at different heating rates. Kinetic parameters of pyrolysis were calculated using model free iso-conversional models. The determined activation energy and pre-exponential factor values were ranged between 184.4 and 311.8 kJ mol(-1) and 3.36E+16-1.23E+28, respectively. Thermodynamic parameters, such as change in enthalpy, Gibbs free energy and entropy were also calculated. DSC plots of samples showed that for all heating rates the reactions showed an exothermic behavior. Evolved gaseous species were investigated simultaneously during pyrolysis using a FTIR spectrometer coupled to TGA system. The change in profile of gaseous product release depending on temperature and heating rate was also studied. Considering kinetic and thermodynamic analysis besides proximate analysis, pea waste has potential for bioenergy production via pyrolysis.en_US
dc.identifier.doi10.1016/j.applthermaleng.2018.03.050
dc.identifier.endpage61en_US
dc.identifier.issn1359-4311
dc.identifier.startpage54en_US
dc.identifier.urihttps://doi.org/10.1016/j.applthermaleng.2018.03.050
dc.identifier.urihttps://hdl.handle.net/20.500.12712/11576
dc.identifier.volume137en_US
dc.identifier.wosWOS:000434491500006
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.journalApplied Thermal Engineeringen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPea Wasteen_US
dc.subjectPyrolysisen_US
dc.subjectTG/DSC-FTIRen_US
dc.subjectKineticsen_US
dc.subjectThermodynamical Parametersen_US
dc.titleThermokinetic and TG/DSC-FTIR Study of Pea Waste Biomass Pyrolysisen_US
dc.typeArticleen_US
dspace.entity.typePublication

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