Publication:
Novel Cobalt(II), Nickel(II) and Copper(II) Complexes of Neutral Orotic Acid. Synthesis, Spectroscopic and Thermal Studies

dc.authorscopusid16403949600
dc.authorscopusid6603711357
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorÖlmez, H.
dc.date.accessioned2020-06-21T15:30:14Z
dc.date.available2020-06-21T15:30:14Z
dc.date.issued2005
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yeşilel] Okan Zafer, Department of Chemistry, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Ölmez] Halis, Department of Chemistry, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractThe new orotic acid complexes, [MCl<inf>2</inf>(H<inf>2</inf>O) <inf>3</inf>(H<inf>3</inf>Or)], M=Co(II), Ni(II) and [CuCl<inf>2</inf>(H <inf>2</inf>O)(H<inf>3</inf>Or)<inf>3</inf>] • H<inf>2</inf>O, were synthesized and characterized by elemental analysis, magnetic susceptibility, spectral (Diffuse reflectance UV-Vis and FTIR) methods, and simultaneous thermal analysis (TG, DTG and DTA) techniques. Physical measurements indicate that the neutral orotic acid ligands are bonded to metal ions through the carbonyl groups. Two thermal processes of the complexes can occur: dehydration and pyrolytic decomposition. On the basis of the DTG<inf>max</inf>, the thermal stability of the complexes follows the order: Co(II) (122 °C) > Cu(II) (77 °C) > Ni(II) (66 °C). © Springer 2005.en_US
dc.identifier.doi10.1007/s11243-005-6289-z
dc.identifier.endpage997en_US
dc.identifier.issn0340-4285
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-26844446369
dc.identifier.scopusqualityQ3
dc.identifier.startpage992en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-005-6289-z
dc.identifier.volume30en_US
dc.identifier.wosWOS:000232626900011
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistryen_US
dc.relation.journalTransition Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleNovel Cobalt(II), Nickel(II) and Copper(II) Complexes of Neutral Orotic Acid. Synthesis, Spectroscopic and Thermal Studiesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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