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Spectroscopic Studies and Crystal Structure of Four-Coordinate Manganese(II) Chloride Complex

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dc.authorscopusid35102910700
dc.authorscopusid35567635300
dc.authorscopusid55905669900
dc.authorscopusid8220216800
dc.contributor.authorOzay, H.
dc.contributor.authorYildiz, M.
dc.contributor.authorÜnver, H.
dc.contributor.authorÍskeleli, N.O.
dc.date.accessioned2020-06-21T14:28:39Z
dc.date.available2020-06-21T14:28:39Z
dc.date.issued2012
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Ozay] Hava, Department of Chemistry, Çanakkale Onsekiz Mart Üniversitesi, Canakkale, Canakkale, Turkey; [Yildiz] Mustafa, Department of Chemistry, Çanakkale Onsekiz Mart Üniversitesi, Canakkale, Canakkale, Turkey, Nanoscience and Technology Research and Application Center (NANORAC), Çanakkale Onsekiz Mart Üniversitesi, Canakkale, Canakkale, Turkey; [Ünver] Hüseyin, Department of Physics, Ankara Üniversitesi, Ankara, Turkey; [Ískeleli] Nazan Ocak, Department of Science Education, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractHigh-spin new, manganese-(II) L <inf>2</inf>MnCl <inf>2</inf>, complex has been synthesized and its structure was elucidated by using elemental analysis, FT-IR, DTA-TG, 1H-NMR, 13C-NMR, and UV-Visible spectroscopic techniques. The structure of the compound has also been examined crystallographically. The title compound crystallizes in the triclinic space group P-1, with unit cell parameters: a = 11.354(1), b = 11.868(1), c = 12.080(1) Å, V = 1548.9(1)Å 3, D <inf>x</inf> = 1.270g.cm -3, and Z = 2, respectively. The Mn atom was tetra-coordinated to form a distorted tetrahedral geometry by two oxygen atoms of L <inf>2</inf> and two chloride atoms of MnCl <inf>2</inf>.4H <inf>2</inf>O in the complex. © 2012 Copyright Taylor and Francis Group, LLC.en_US
dc.identifier.doi10.1080/15533174.2011.618756
dc.identifier.endpage877en_US
dc.identifier.issn1553-3174
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-84864044122
dc.identifier.startpage872en_US
dc.identifier.urihttps://doi.org/10.1080/15533174.2011.618756
dc.identifier.urihttps://hdl.handle.net/20.500.12712/16782
dc.identifier.volume42en_US
dc.identifier.wosWOS:000306319300017
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistryen_US
dc.relation.journalSynthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrystal Structureen_US
dc.subjectDTA-TGen_US
dc.subjectFour-Coordinated Manganese(II)en_US
dc.subjectNMRen_US
dc.subjectSpectroscopic Studiesen_US
dc.titleSpectroscopic Studies and Crystal Structure of Four-Coordinate Manganese(II) Chloride Complexen_US
dc.typeArticleen_US
dspace.entity.typePublication

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