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3-[(Diphenylphosphinothioyl)oxy] Diphenylphosphanylthioate

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dc.authorwosidKaraman, Merve/Abu-7294-2022
dc.authorwosidKaraman, Merve/Abu-7294-2022
dc.contributor.authorKaraman, Merve
dc.contributor.authorIrisli, Sevil
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorIDKaraman, Merve/0000-0003-2803-7414
dc.date.accessioned2020-06-21T09:37:54Z
dc.date.available2020-06-21T09:37:54Z
dc.date.issued2014
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Karaman, Merve; Irisli, Sevil] Univ Ege, Fac Sci, Dept Chem, TR-35100 Izmir, Turkey; [Buyukgungor, Orhan] Univ Ondokuzmayis, Fac Sci, Dept Phys, TR-55139 Samsun, Turkeyen_US
dc.descriptionKaraman, Merve/0000-0003-2803-7414;en_US
dc.description.abstractThe title salt, C16H21NOPS+center dot C12H10OPS, was synthesized from the reaction between 3-(methylamino)propan-1-ol and PPh2(S) Cl in the presence of Et3N. Its structure has been identified using spectroscopic methods and X-ray analysis. Single crystals were obtained from ethanol by slow evaporation. In the asymmetric unit, a cation-anion pair is formed through an intermolecular N-H center dot center dot center dot O [N center dot center dot center dot O = 2.6974 (18) angstrom] hydrogen bond. The molecules are packed through N-H center dot center dot center dot O and N-H center dot center dot center dot S hydrogen bonds in the crystal and these hydrogen bonds are responsible for the high melting point. The P atoms of the anion and cation both have distorted tetrahedral environments.en_US
dc.description.sponsorshipResearch Foundation of Ege University [2012 FEN 048]; TUBITAK [110 T786]en_US
dc.description.sponsorshipWe thank Ondokuz Mayis University for X-ray crystallography support, the Research Foundation of Ege University for funding (grant No. 2012 FEN 048) and TUBITAK (grant No. 110 T786).en_US
dc.description.woscitationindexScience Citation Index Expanded
dc.identifier.doi10.1107/S2053229614002757
dc.identifier.endpageU272en_US
dc.identifier.issn0108-2701
dc.identifier.issn1600-5759
dc.identifier.issue3en_US
dc.identifier.pmid24594726
dc.identifier.startpage320en_US
dc.identifier.urihttps://doi.org/10.1107/S2053229614002757
dc.identifier.volume70en_US
dc.identifier.wosWOS:000332221900016
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.journalActa Crystallographica Section C: Structural Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrystal Structureen_US
dc.subject3-[(Diphenylphosphinothioyl)oxy]-N-Methylpropan-1-Aminiumen_US
dc.subjectDiphenylphosphanylthioateen_US
dc.subjectHydrogen Bondingen_US
dc.subjectSpectroscopic Analysisen_US
dc.subjectHigh Melting Pointen_US
dc.title3-[(Diphenylphosphinothioyl)oxy] Diphenylphosphanylthioateen_US
dc.typeArticleen_US
dspace.entity.typePublication

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