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Synthesis, Spectral Characterization and Electrochemistry of Vanadium(V) Complex With Tryptophan

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dc.authorscopusid55774433600
dc.authorscopusid6603524165
dc.contributor.authorÇakir, S.
dc.contributor.authorBi̇Çer, E.
dc.date.accessioned2020-06-21T14:48:10Z
dc.date.available2020-06-21T14:48:10Z
dc.date.issued2010
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Çakir] Semiha, Department of Chemistry, Gazi Üniversitesi, Ankara, Ankara, Turkey; [Bi̇Çer] Ender, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractA new oxovanadium(V) complex of NH<inf>4</inf>VO<inf>3</inf> and tryptophan (TrpH) has been synthesized in aqueous solution at pH 6.0 and characterized by elemental analysis, UV-Vis, FT-IR, 1H-NMR and mass spectroscopic data. The complex (Na<inf>4</inf>[V<inf>3</inf>O<inf>9</inf>(Trp)]) was diamagnetic in nature as was evident from the electron spin resonance spectroscopy (ESR) and the magnetic susceptibility measurements, in conformity with the presence of vanadium(V) in the structure. The electrochemical behaviour of Na<inf>4</inf>[V<inf>3</inf>O<inf>9</inf>(Trp)] complex was also studied on the hanging mercury drop electrode (HMDE) by using cyclic voltammetry (CV). The cyclic voltammograms of Na<inf>4</inf>[V<inf>3</inf>O<inf>9</inf>(Trp)] complex exhibit two new reduction waves at -0.38 V and -1.01 V in Britton-Robinson buffer (pH 6.0) for the potential range from 0.0 V to -1.2 V.en_US
dc.identifier.doi10.4067/S0717-97072010000200020
dc.identifier.endpage239en_US
dc.identifier.issn0717-9324
dc.identifier.issn0717-9707
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-77956949743
dc.identifier.scopusqualityQ2
dc.identifier.startpage236en_US
dc.identifier.urihttps://doi.org/10.4067/S0717-97072010000200020
dc.identifier.volume55en_US
dc.identifier.wosWOS:000279984400020
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherSociedad Chilena de Químicaen_US
dc.relation.ispartofJournal of the Chilean Chemical Societyen_US
dc.relation.journalJournal of the Chilean Chemical Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectSpectroscopyen_US
dc.subjectTryptophanen_US
dc.subjectVanadium Complexesen_US
dc.subjectVoltammetryen_US
dc.titleSynthesis, Spectral Characterization and Electrochemistry of Vanadium(V) Complex With Tryptophanen_US
dc.typeArticleen_US
dspace.entity.typePublication

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