Sonochemical Syntheses of Strawberry-Like Nano-Structure Mixed-Ligand Lead(II) Coordination Polymer: Thermal, Structural and X-Ray Powder Diffraction Studies

Abstract

Nano-structure of a new Pb(II) two-dimensional coordination polymer, {[Pb(2-pyc)(N<inf>3</inf>)(H<inf>2</inf>O)]<inf>n</inf> (1), 2-Hpyc = 2-pyridinecarboxylic acid} was synthesized by a sonochemical method. The new nano-structure was characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses. Compound 1 was structurally characterized by single crystal X-ray diffraction and consists of two-dimensional polymeric units. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses and compared. PbO nano-powder was obtained by calcination of the nano-structure of compound 1 at 400 °C. This study demonstrates the coordination polymers may be suitable precursors for the preparation of nano-scale materials and dependent on their packing they may produce different and interesting morphologies. © 2009 Elsevier B.V. All rights reserved.