Publication:
The Synthesis, Structural Characterization and Conformational Analysis of (1,3-Bis(2 5-Cyclooctadiene)rhodium(I)

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dc.authorscopusid8839071200
dc.authorscopusid16052784700
dc.authorscopusid56249121800
dc.authorscopusid7006471258
dc.authorscopusid36039473500
dc.contributor.authorKarabiyik, H.
dc.contributor.authorKilinçarslan, R.
dc.contributor.authorAygün, M.
dc.contributor.authorÇetinkaya, B.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2025-12-10T20:59:59Z
dc.date.issued2005
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Karabiyik] Hasan, Edebiyat Fakültesi, Dokuz Eylül Üniversitesi, Izmir, Turkey; [Kilinçarslan] Rafet, Department of Chemistry, Ege Üniversitesi, Izmir, Turkey; [Aygün] Muhittin, Edebiyat Fakültesi, Dokuz Eylül Üniversitesi, Izmir, Turkey; [Çetinkaya] Bekir, Department of Chemistry, Ege Üniversitesi, Izmir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractA four-coordinated Rh(I) complex with a new heterocyclic carbene ligand, functionalized by amino donor pendants, 4, was synthesized and characterized by elemental analyses, NMR and IR spectroscopy, and the molecular structure of the title compound has been determined by X-ray crystallography. Crystallographic data: monoclinic, P2<inf>1</inf>/m, a = 7.9307(5), b = 25.0061(12), c = 8.0780(6) Å, β = 101.366(6)°, V = 1570.58(17) Å3, ρ<inf>calc</inf> = 1.3515(1) g cm-3, Z = 2. The experimentally obtained structural parameters for compound 4 compare reasonably well with those calculated at the semi-empirical ZINDO/1 level of theory carried out to elucidate conformational flexibility and steric hindrances. © 2005 Verlag der Zeitschrift für Naturforschung.en_US
dc.identifier.doi10.1515/znb-2005-0804
dc.identifier.endpage842en_US
dc.identifier.issn0932-0776
dc.identifier.issn1865-7117
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-24944545284
dc.identifier.scopusqualityQ3
dc.identifier.startpage837en_US
dc.identifier.urihttps://doi.org/10.1515/znb-2005-0804
dc.identifier.urihttps://hdl.handle.net/20.500.12712/34449
dc.identifier.volume60en_US
dc.identifier.wosqualityQ4
dc.language.isoenen_US
dc.publisherVerlag der Zeitschrift fur Naturforschungen_US
dc.relation.ispartofZeitschrift Für Naturforschung Section B-A Journal of Chemical Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCarbene Liganden_US
dc.subjectCrystal Structureen_US
dc.subjectN-Heterocyclic Carbenesen_US
dc.subjectRhodium Complexesen_US
dc.subjectZINDO/1en_US
dc.titleThe Synthesis, Structural Characterization and Conformational Analysis of (1,3-Bis(2 5-Cyclooctadiene)rhodium(I)en_US
dc.typeArticleen_US
dspace.entity.typePublication

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