Publication:
Structural and Spectroscopic Studies on Cadmium Complex of a Biogenic Amine, Histamine

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dc.authorscopusid8205282600
dc.authorscopusid6603689883
dc.authorscopusid6603897211
dc.authorscopusid6602801811
dc.contributor.authorKaştaş, G.
dc.contributor.authorPaşaoĝlu, H.
dc.contributor.authorKarabulut, B.
dc.contributor.authorBulut, I.
dc.date.accessioned2020-06-21T14:49:04Z
dc.date.available2020-06-21T14:49:04Z
dc.date.issued2010
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kaştaş] Gökhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Paşaoĝlu] Hümeyra, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Karabulut] Bünyamin, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Bulut] Iclal, Department of Chemistry, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractA novel histamine-saccharine complex, [Cd(His)<inf>2</inf>(Sac)<inf>2</inf>], is investigated by X-ray diffraction, infrared (IR) and electron paramagnetic resonance (EPR) spectroscopies. In the complex, histamine has Nτ-H tautomeric form. The crystal packing is stabilized by N-H⋯O hydrogen bonds forming R<inf>2</inf>2 (16) and R<inf>4</inf>2 (4) ring patterns. In EPR study, the angular variation of the spectra of Cu2+ doped Cd(His)<inf>2</inf>(Sac)<inf>2</inf> single crystal shows that two different Cu2+ complexes are located in different chemical environments. Each environment contains one magnetically distinct Cu2+ site occupying substitutional position in the lattice. The vibrational investigation has been carried out on the basis of some characteristic IR bands of histamine and saccharine molecules. © 2010 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.cplett.2010.02.011
dc.identifier.endpage167en_US
dc.identifier.issn0009-2614
dc.identifier.scopus2-s2.0-77649342606
dc.identifier.scopusqualityQ2
dc.identifier.startpage162en_US
dc.identifier.urihttps://doi.org/10.1016/j.cplett.2010.02.011
dc.identifier.volume488en_US
dc.identifier.wosWOS:000275751900012
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.relation.journalChemical Physics Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleStructural and Spectroscopic Studies on Cadmium Complex of a Biogenic Amine, Histamineen_US
dc.typeArticleen_US
dspace.entity.typePublication

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