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Synthesis, Spectroscopy, Thermal Behaviour and Molecular Structure of Orotatotriethanolaminecopper(II) Monohydrate

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dc.authorscopusid6603711357
dc.authorscopusid55159584400
dc.authorscopusid16403949600
dc.authorscopusid7006893434
dc.authorscopusid7005759139
dc.contributor.authorÖlmez, H.
dc.contributor.authorÍçbudak, H.
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorArici, C.
dc.contributor.authorÜlkü, D.
dc.date.accessioned2020-06-21T15:43:37Z
dc.date.available2020-06-21T15:43:37Z
dc.date.issued2004
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Ölmez] Halis, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Íçbudak] Hasan, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Arici] Cengíz, Department of Physics Engineering, Hacettepe Üniversitesi, Ankara, Turkey; [Ülkü] Dínçer, Department of Physics Engineering, Hacettepe Üniversitesi, Ankara, Turkeyen_US
dc.description.abstractThe orotatotriethanolaminecopper(II) monohydrate, [Cu(C<inf>5</inf>H <inf>2</inf>N<inf>2</inf>O<inf>4</inf>)(C<inf>6</inf>H<inf>15</inf>NO <inf>3</inf>)] · H<inf>2</inf>O, has been synthesized and characterized with physico-chemical methods (IR and UV-Vis spectroscopy, magnetic susceptibility, conductivity and thermoanalytical measurements) and X-ray diffraction. The structure derived from physico-chemical methods is consistent with that of the X-ray diffraction. The compound crystallizes in the monoclinic system, space group P21/n, with a = 8.6282(12), b = 16.9919(18), c = 10.6985(15) Å, β = 110.08(3)°, V = 1473.1(3) Å3, Z = 4. The copper atom is chelated by the deprotonated nitrogen pyrimidine atom and by the carboxylate oxygen atom of the orotate dianion ligand, and by the nitrogen and oxygen atoms of the triethanolamine ligand. The title compound has a distorted octahedral coordination geometry.en_US
dc.identifier.doi10.1524/zkri.219.5.300.32749
dc.identifier.endpage304en_US
dc.identifier.issn0044-2968
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-8744229789
dc.identifier.startpage300en_US
dc.identifier.urihttps://doi.org/10.1524/zkri.219.5.300.32749
dc.identifier.volume219en_US
dc.identifier.wosWOS:000222068800007
dc.language.isoenen_US
dc.publisherWalter de Gruyter GmbHen_US
dc.relation.ispartofZeitschrift für Kristallographieen_US
dc.relation.journalZeitschrift Fur Kristallographieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCu(II) Complexen_US
dc.subjectIR and UV-Vis Spectraen_US
dc.subjectOrotato and TEA Ligandsen_US
dc.subjectSingle Crystal Structure Analysisen_US
dc.subjectX-Ray Diffractionen_US
dc.titleSynthesis, Spectroscopy, Thermal Behaviour and Molecular Structure of Orotatotriethanolaminecopper(II) Monohydrateen_US
dc.typeArticleen_US
dspace.entity.typePublication

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