Publication: Synthesis, IR Spectra, Thermal Analysis and Crystal Structure of a One-Dimensional Coordination Polymer Containing Both Three- and Four-Coordinate Silver(I) Centers Bridged by Both Saccharinate and N-(2 Ligands
| dc.authorscopusid | 6603157555 | |
| dc.authorscopusid | 58717985000 | |
| dc.authorscopusid | 15033124400 | |
| dc.contributor.author | Hamamci, S. | |
| dc.contributor.author | Yilmaz, V.T. | |
| dc.contributor.author | Harrison, W.T.A. | |
| dc.date.accessioned | 2020-06-21T15:37:23Z | |
| dc.date.available | 2020-06-21T15:37:23Z | |
| dc.date.issued | 2005 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Hamamci] Sevim, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Harrison] William T.A., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdom | en_US |
| dc.description.abstract | A novel [Ag <inf>2</inf>(μ-sac) <inf>2</inf>(μ-hep) <inf>2</inf>] <inf>n</inf> [sac=saccharinate and hep={N-(2-hydroxyethyl)piperazine}] was synthesized and characterized. [Ag <inf>2</inf>(μ-sac) <inf>2</inf>(μ-hep) <inf>2</inf>] <inf>n</inf> consists of dimeric [Ag <inf>2</inf>(μ-sac) <inf>2</inf>] units bridged by the hep ligands, resulting a one-dimensional coordination polymer. [Ag <inf>2</inf>(μ-sac) <inf>2</inf>(μ-hep) <inf>2</inf>] <inf>n</inf> contains two different silver(I) centers with a Ag-Ag separation of 3.492(2) Å. One of the silver(I) ion is trigonal planar to the imino N and carbonyl O atoms of two sac ligands and one of the N atom of hep, while the other silver(I) ion is tetrahedrally coordinated by the N and carbonyl O atoms of two sac ligands and the N and O chelating hep ligand. © 2004 Elsevier B.V. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/j.molstruc.2004.09.023 | |
| dc.identifier.endpage | 195 | en_US |
| dc.identifier.issn | 0022-2860 | |
| dc.identifier.scopus | 2-s2.0-10644226948 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | 191 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.molstruc.2004.09.023 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/21215 | |
| dc.identifier.volume | 734 | en_US |
| dc.identifier.wos | WOS:000226346400025 | |
| dc.identifier.wosquality | Q2 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Science BV | en_US |
| dc.relation.ispartof | Journal of Molecular Structure | en_US |
| dc.relation.journal | Journal of Molecular Structure | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | N-(2-Hydroxyethyl)Piperazine | en_US |
| dc.subject | One-Dimensional Polymer | en_US |
| dc.subject | Saccharin | en_US |
| dc.subject | Silver(I) | en_US |
| dc.title | Synthesis, IR Spectra, Thermal Analysis and Crystal Structure of a One-Dimensional Coordination Polymer Containing Both Three- and Four-Coordinate Silver(I) Centers Bridged by Both Saccharinate and N-(2 Ligands | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |