Publication: Synthesis, Characterization, and Crystal Structures of a Novel [Zn 3(Bba)6(3-Pic)2] Complex (Bba = 2-Benzoylbenzoat, 3-Pic = 3-Picoline)
| dc.authorscopusid | 7005505517 | |
| dc.authorscopusid | 12545386000 | |
| dc.authorscopusid | 56572185100 | |
| dc.contributor.author | Caglar, S. | |
| dc.contributor.author | Heren, Z. | |
| dc.contributor.author | Yıldırım, M.H. | |
| dc.date.accessioned | 2020-06-21T14:41:27Z | |
| dc.date.available | 2020-06-21T14:41:27Z | |
| dc.date.issued | 2011 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Caglar] Sema, Department of Chemistry, Erzincan Binali Yıldırım Üniversitesi, Erzincan, Turkey; [Heren] Zerrin, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yıldırım] M. Hakkı, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey | en_US |
| dc.description.abstract | A novel trinuclear hekzakis(μ<inf>6</inf>-2-benzoylbenzoato-O,O')-bis(3- picoline)-tri-zinc(II) complex, [Zn<inf>3</inf>(bba)<inf>6</inf>(3-pic) <inf>2</inf>] has been synthesized and characterized by elemental analysis, Fourier-transform infrared (FT-IR), ultraviolet/visible (UV/Vis), and mass spectroscopy, thermal methods, and single-crystal x-ray diffraction. The three Zn(II) centers are in two different coordination environments. The central Zn(II) is in a distorted octahedral geometry, while the two terminal Zn(II) centers adopt a distorted tetrahedral geometry. The central and the terminal metal centers are connected through tri μ-2-benzoylbenzoato-O,O' bridges. The crystal packing of the trinuclear complex is stabilized by C-H ⋯π interaction between bba ligands. The characteristics of the carboxylate anions with typical (OCO)<inf>asym</inf>and (OCO)<inf>sym</inf> values are 1594 and 1368 cm-1, respectively. Copyright © Taylor & Francis Group, LLC. | en_US |
| dc.identifier.doi | 10.1080/15533174.2011.591338 | |
| dc.identifier.endpage | 1027 | en_US |
| dc.identifier.issn | 1553-3174 | |
| dc.identifier.issue | 8 | en_US |
| dc.identifier.scopus | 2-s2.0-80053653836 | |
| dc.identifier.startpage | 1022 | en_US |
| dc.identifier.uri | https://doi.org/10.1080/15533174.2011.591338 | |
| dc.identifier.volume | 41 | en_US |
| dc.identifier.wos | WOS:000296318800017 | |
| dc.language.iso | en | en_US |
| dc.publisher | Taylor & Francis Inc | en_US |
| dc.relation.ispartof | Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry | en_US |
| dc.relation.journal | Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | 2-Benzoylbenzoic Acid | en_US |
| dc.subject | 3-Picoline | en_US |
| dc.subject | Crystal Structure | en_US |
| dc.subject | Trinuclear Zinc(II) Complexes | en_US |
| dc.title | Synthesis, Characterization, and Crystal Structures of a Novel [Zn 3(Bba)6(3-Pic)2] Complex (Bba = 2-Benzoylbenzoat, 3-Pic = 3-Picoline) | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |