Publication:
Synthesis, Characterization and Catalytic Activity of N-Heterocyclic Carbene Ligated Schiff Base Palladacycles

dc.authorscopusid15126857900
dc.authorscopusid57118356500
dc.authorscopusid8398877200
dc.authorscopusid11439933100
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.authorwosidBabahan-Bircan, Ilknur/Gwc-6082-2022
dc.authorwosidBabahan-Bircan, Ilknur/Aag-9846-2020
dc.authorwosidFirinci, Rukiye/Khd-3085-2024
dc.contributor.authorBabahan, Ilknur
dc.contributor.authorFirinci, Rukiye
dc.contributor.authorOzdemir, Namik
dc.contributor.authorGunay, M. Emin
dc.contributor.authorIDFirinci, Rukiye/0000-0003-2661-8266
dc.contributor.authorIDÖzdemir, Namık/0000-0003-3371-9874
dc.contributor.authorIDBabahan-Bircan, Ilknur/0000-0002-1336-671X
dc.date.accessioned2025-12-11T01:25:11Z
dc.date.issued2021
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Babahan, Ilknur; Firinci, Rukiye; Gunay, M. Emin] Adnan Menderes Univ, Dept Chem, TR-09010 Aydin, Turkey; [Ozdemir, Namik] Ondokuz Mayis Univ, Dept Math & Sci Educ, TR-55139 Samsun, Turkeyen_US
dc.descriptionFirinci, Rukiye/0000-0003-2661-8266; Özdemir, Namık/0000-0003-3371-9874; Babahan-Bircan, Ilknur/0000-0002-1336-671X;en_US
dc.description.abstractA series of N-heterocyclic carbene (NHC) ligated Schiff base palladacycles were synthesized by the reaction of ?-acetato-bridged Schiff base palladacycles (PdL1-2) with imidazolium salts (a-c). The new NHC ligated palladacycles were fully characterized using 1H NMR, 13C NMR, infrared spectroscopy, MS analysis, and single-crystal X-ray diffraction for one complex (PdL1). Further exploration of the catalytic application of the palladacycles for Suzuki-Miyaura cross-coupling reactions of aryl bromides with phenylboronic acid was carried out. It was determined that the new dimeric imine-palladacycle (PdL2) exhibits the highest catalytic activity among the coupling compounds in this study.en_US
dc.description.sponsorshipTUBITAK [104T203]; Ondokuz Mayis University [PYO.FEN.1906.19.001]en_US
dc.description.sponsorshipFunding of our research from the TUBITAK (Project No: 104T203) and Ondokuz Mayis University (Project No: PYO.FEN.1906.19.001) are gratefully acknowledged.en_US
dc.description.woscitationindexScience Citation Index Expanded
dc.identifier.doi10.1016/j.ica.2021.120360
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-85104130309
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.ica.2021.120360
dc.identifier.urihttps://hdl.handle.net/20.500.12712/43590
dc.identifier.volume522en_US
dc.identifier.wosWOS:000646261700001
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectImine-Palladacycleen_US
dc.subjectN-Heterocyclic Carbeneen_US
dc.subjectSchiff Baseen_US
dc.subjectImidazol-2-Ylideneen_US
dc.subjectCatalysisen_US
dc.subjectSuzuki-Miyaura Cross-Coupling Reactionen_US
dc.titleSynthesis, Characterization and Catalytic Activity of N-Heterocyclic Carbene Ligated Schiff Base Palladacyclesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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