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A Combined Experimental and Theoretical Investigation of a New Imineoxime and Its Palladium(II) and Platinum(II) Complexes: Synthesis, Structural Characterization and Spectroscopic Properties

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dc.authorscopusid35181446100
dc.authorscopusid55551960400
dc.authorscopusid58717985000
dc.authorscopusid36039473500
dc.contributor.authorKaya, Y.
dc.contributor.authorIcsel, C.
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T13:52:09Z
dc.date.available2020-06-21T13:52:09Z
dc.date.issued2014
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kaya] Yunus, Department of Chemistry, Bursa Uludağ Üniversitesi, Bursa, Bursa, Turkey; [Icsel] Ceyda, Department of Chemistry, Bursa Uludağ Üniversitesi, Bursa, Bursa, Turkey; [Yilmaz] Veysel T., Department of Chemistry, Bursa Uludağ Üniversitesi, Bursa, Bursa, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractA new imineoxime compound {(1E,2E)-(2-hydroxy-ethylimino)-naphthalene-2yl- ethanal oxime (heineoH)} and its palladium(II) and platinum(II) complexes ([M(heineo)<inf>2</inf>]) have been synthesized and characterized by IR, NMR, UV-vis, elemental analysis, mass spectra and X-ray single crystal diffraction. [Pt(heineo)<inf>2</inf>] was obtained as a single crystal, while [Pd(heineo)<inf>2</inf>] was synthesized as a polycrystalline powder. The X-ray diffraction analysis of the [Pt(heineo)<inf>2</inf>] indicated that the platinum(II) ion is coordinated by two heineo ligands in a distorted square-planar geometry. DFT (B3LYP/6-311++G(d,p) and LANL2DZ) calculations on the ligand and its complexes were carried out to correlate the geometry and vibrational and electronic properties. Additionally, heineoH is fluorescent in EtOH at room temperature, but the fluorescence is quenched in the case of the metal complexes. © 2014 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.saa.2014.05.055
dc.identifier.endpage101en_US
dc.identifier.issn1386-1425
dc.identifier.pmid24929321
dc.identifier.scopus2-s2.0-84902505966
dc.identifier.scopusqualityQ1
dc.identifier.startpage93en_US
dc.identifier.urihttps://doi.org/10.1016/j.saa.2014.05.055
dc.identifier.volume133en_US
dc.identifier.wosWOS:000340330900015
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopyen_US
dc.relation.journalSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrystal Structureen_US
dc.subjectDFT Calculationsen_US
dc.subjectFluorescenceen_US
dc.subjectImineoximeen_US
dc.subjectPalladium(II)en_US
dc.subjectPlatinum(II)en_US
dc.titleA Combined Experimental and Theoretical Investigation of a New Imineoxime and Its Palladium(II) and Platinum(II) Complexes: Synthesis, Structural Characterization and Spectroscopic Propertiesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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