Publication: New (κ2-C,N) Complexes with Benzimidazol-2 Ligand: Synthesis, Crystal Structures and Characterization
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Abstract
Reaction of unsymmetrical benzimidazolium bromides (1) with Ag<inf>2</inf>O and subsequent transmetallation with chloro-bridged dinuclear palladacycle, [Pd(dmba)(μ-Cl)]<inf>2</inf> (dmba: N,N-dimethylbenzylamine) afforded benzannulated monocarbene complexes [Pd(dmba)(NHC)Cl], 2. The palladacycles (2a-c) were characterized by elemental analysis; NMR spectroscopy and the molecular structure of 2a and 2c were determined by X-ray crystallography. © 2009 Elsevier B.V. All rights reserved.
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Source
Inorganic Chemistry Communications
Volume
12
Issue
10
Start Page
990
End Page
993