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Bis(2-Pyridylmethanol)bis(saccharinato)zinc(II) and-Cadmium(II) at 120 K: Three-Dimensional Structures Containing Both N- and O-Coordinated Ambidentate Saccharinate Ligands

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dc.authorscopusid58717985000
dc.authorscopusid6603070940
dc.authorscopusid6603822664
dc.authorscopusid15033124400
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorGuney, S.
dc.contributor.authorAndaç, O.
dc.contributor.authorHarrison, W.T.A.
dc.date.accessioned2020-06-21T15:45:34Z
dc.date.available2020-06-21T15:45:34Z
dc.date.issued2002
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Guney] Serkan, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Andaç] Ömer, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Harrison] William T.A., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe title complexes [M(sac)<inf>2</inf>(mpy)<inf>2</inf>] [sac is saccharinate (C<inf>7</inf>H<inf>4</inf>NO<inf>3</inf>S) and mpy is 2-pyridylmethanol (C<inf>6</inf>H<inf>7</inf>NO)], with M = ZnII and CdII, are isostructural and consist of neutral molecules. The ZnII or CdII cations are octahedrally coordinated by the two neutral ropy and two anionic sac ligands. The mpy ligand acts as a bidentate donor through the amine N and hydroxyl O atoms. The sac ligands exhibit an ambidentate coordination behaviour; one is N-coordinated and the other is O-coordinated within the same coordination octahedron. The crystal packing is determined by C-H⋯O-type hydrogen bonding, as well as by weak py-py and sac-sac aromatic π-π-stacking interactions.en_US
dc.identifier.doi10.1107/S0108270102010491
dc.identifier.endpagem430en_US
dc.identifier.issn0108-2701
dc.identifier.issn1600-5759
dc.identifier.issue8en_US
dc.identifier.pmid12154282
dc.identifier.scopus2-s2.0-0036672119
dc.identifier.startpagem427en_US
dc.identifier.urihttps://doi.org/10.1107/S0108270102010491
dc.identifier.volume58en_US
dc.identifier.wosWOS:000177172100004
dc.language.isoenen_US
dc.publisherBlackwell Munksgaarden_US
dc.relation.ispartofActa Crystallographica Section C: Crystal Structure Communicationsen_US
dc.relation.journalActa Crystallographica Section C-Crystal Structure Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleBis(2-Pyridylmethanol)bis(saccharinato)zinc(II) and-Cadmium(II) at 120 K: Three-Dimensional Structures Containing Both N- and O-Coordinated Ambidentate Saccharinate Ligandsen_US
dc.typeArticleen_US
dspace.entity.typePublication

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