Publication:
The Synthesis of Sulfinylphthalimides and Their Reactions With Some Nucleophiles in Dioxane

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dc.authorscopusid54879965200
dc.authorscopusid6701793097
dc.contributor.authorBozkurt, Y.S.
dc.contributor.authorKütük, H.
dc.date.accessioned2020-06-21T14:46:28Z
dc.date.available2020-06-21T14:46:28Z
dc.date.issued2011
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Bozkurt] Yasemin Soydaş, Department of Chemistry, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Kütük] Halil, Department of Chemistry, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractIn this study, some N-(p-substituted-arylsulfinyl)phthalimides (1a-1e) were synthesized. The synthesized compounds were examined with respect to their substitution reactions with sodium ethoxide, sodium methoxide, methylamine, and t-butylamine in dioxane. The substituent effect was investigated at 30.0 ± 0.1 °C. The activation entropy was also studied, and negative ΔS ≠= values were obtained. Configuration inversions were observed in the substitution reactions. This result is in conformity with the S <inf>N</inf>2 mechanism. Copyright © Taylor & Francis Group, LLC.en_US
dc.identifier.doi10.1080/10426507.2011.561457
dc.identifier.endpage2257en_US
dc.identifier.issn1042-6507
dc.identifier.issn1563-5325
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-84855829734
dc.identifier.scopusqualityQ4
dc.identifier.startpage2250en_US
dc.identifier.urihttps://doi.org/10.1080/10426507.2011.561457
dc.identifier.volume186en_US
dc.identifier.wosWOS:000299727600012
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofPhosphorus Sulfur and Silicon and the Related Elementsen_US
dc.relation.journalPhosphorus Sulfur and Silicon and the Related Elementsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectActivation Entropyen_US
dc.subjectArylsulfinylphthalimidesen_US
dc.subjectSN2en_US
dc.subjectSolvent Effecten_US
dc.subjectSubstituent Effecten_US
dc.titleThe Synthesis of Sulfinylphthalimides and Their Reactions With Some Nucleophiles in Dioxaneen_US
dc.typeArticleen_US
dspace.entity.typePublication

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