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Synthesis, Spectroscopic and Thermal Studies of the Copper(II) Aspartame Chloride Complex

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dc.authorscopusid55774433600
dc.authorscopusid7004269359
dc.authorscopusid7006839507
dc.authorscopusid6603524165
dc.authorscopusid6602801811
dc.authorscopusid55159584400
dc.authorscopusid55159584400
dc.contributor.authorÇakir, S.
dc.contributor.authorÇoşkun, E.
dc.contributor.authorNaumov, P.
dc.contributor.authorBi̇Çer, E.
dc.contributor.authorBulut, I.
dc.contributor.authorÍçbudak, H.
dc.contributor.authorÇakir, O.
dc.date.accessioned2020-06-21T15:48:48Z
dc.date.available2020-06-21T15:48:48Z
dc.date.issued2002
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Çakir] Semiha, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Çoşkun] Emine, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Naumov] PanČe, Institute of Chemistry, Ss. Cyril and Methodius University in Skopje, Skopje, North Macedonia; [Bi̇Çer] Ender, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Bulut] Iclal, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Íçbudak] Hasan, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Çakir] Osman, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractAspartame adduct of copper(II) chloride Cu(AsP)<inf>2</inf>Cl<inf>2</inf>·2H<inf>2</inf>O (Asp = aspartame) is synthesized and characterized by elemental analysis, FT IR, UV/vis, ESR spectroscopies, TG, DTG, DTA measurements and molecular mechanics calculations. Aqueous solution of the green solid absorbs strongly at 774 and 367 nm. According to the FT IR spectra, the aspartame moiety coordinates to the copper(II) ion via its carboxylate ends, whereas the ammonium terminal groups give rise to hydrogen bonding network with the water, the chloride ions or neighboring carboxylate groups. The results suggest tetragonally distorted octahedral environment of the copper ions. © 2002 Elsevier Science B.V. All rights reserved.en_US
dc.identifier.doi10.1016/S0022-2860(01)00939-5
dc.identifier.endpage107en_US
dc.identifier.issn0022-2860
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-0037042162
dc.identifier.scopusqualityQ1
dc.identifier.startpage101en_US
dc.identifier.urihttps://doi.org/10.1016/S0022-2860(01)00939-5
dc.identifier.urihttps://hdl.handle.net/20.500.12712/22030
dc.identifier.volume608en_US
dc.identifier.wosWOS:000174630200014
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherElsevier Science BVen_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.journalJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAspartameen_US
dc.subjectCopperen_US
dc.subjectESRen_US
dc.subjectFT-IRen_US
dc.subjectThermal Analysisen_US
dc.subjectUV/Visen_US
dc.titleSynthesis, Spectroscopic and Thermal Studies of the Copper(II) Aspartame Chloride Complexen_US
dc.typeArticleen_US
dspace.entity.typePublication

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