Publication: A New One-Dimensional Coordination Polymer of Silver(I) With Bridging 2-(2-Aminoethyl)pyridine and Nitrato Ligands: [Ag2(μ–NO3)2(μ–Aepy)2]n
| dc.authorscopusid | 7801406100 | |
| dc.authorscopusid | 58717985000 | |
| dc.authorscopusid | 15033124400 | |
| dc.contributor.author | Senel, E. | |
| dc.contributor.author | Yilmaz, V.T. | |
| dc.contributor.author | Harrison, W.T.A. | |
| dc.date.accessioned | 2025-12-10T21:00:01Z | |
| dc.date.issued | 2005 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Senel] Evrim, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Harrison] William T.A., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdom | en_US |
| dc.description.abstract | A new silver(I) nitrate complex of 2-(2-aminoethyl)pyridine (aepy), [Ag<inf>2</inf>(μ-NO<inf>3</inf>)<inf>2</inf>(μ-aepy)<inf>2</inf>] <inf>n</inf>, has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffractometry. Two silver(I) ions are doubly bridged by two bidentate aepy ligands forming dimeric building block [Ag<inf>2</inf>(μ-aepy)<inf>2</inf>] units with a Ag⋯Ag distance of 3.0587(17) Å. These dimeric units are further doubly bridged by two nitrato ligands into a one-dimensional polymeric chain. The nitrato ligand exhibits an uncommon bidentate bridging mode of Ag-ONO-Ag. The title complex features a hydrogen bonded two-dimensional supramolecular framework formed via N-H⋯O hydrogen bonds, involving the uncoordinated O atom of the nitrate ligand and amine hydrogen atoms of aepy. The thermal stability of the title complex was investigated using thermogravimetry and differential thermal analysis. © 2005 Verlag der Zeitschrift für Naturforschung. | en_US |
| dc.identifier.doi | 10.1515/znb-2005-0608 | |
| dc.identifier.endpage | 662 | en_US |
| dc.identifier.issn | 0932-0776 | |
| dc.identifier.issn | 1865-7117 | |
| dc.identifier.issue | 6 | en_US |
| dc.identifier.scopus | 2-s2.0-21244463473 | |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.startpage | 659 | en_US |
| dc.identifier.uri | https://doi.org/10.1515/znb-2005-0608 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/34450 | |
| dc.identifier.volume | 60 | en_US |
| dc.identifier.wosquality | Q4 | |
| dc.language.iso | en | en_US |
| dc.publisher | Verlag der Zeitschrift fur Naturforschung | en_US |
| dc.relation.ispartof | Zeitschrift Für Naturforschung Section B-A Journal of Chemical Sciences | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | 2-(2-Aminoethyl)-Pyridine | en_US |
| dc.subject | Crystal Structure | en_US |
| dc.subject | Nitrato | en_US |
| dc.subject | One-Dimensional Coordination Polymer | en_US |
| dc.subject | Silver(I) | en_US |
| dc.title | A New One-Dimensional Coordination Polymer of Silver(I) With Bridging 2-(2-Aminoethyl)pyridine and Nitrato Ligands: [Ag2(μ–NO3)2(μ–Aepy)2]n | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |