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Mono- and Dinuclear Copper(II) Naproxenato Complexes Containing 3-Picoline and 4-Picoline: Synthesis, Structure, Properties, Catechol Oxidase, and Antimicrobial Activities

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dc.authorscopusid7005505517
dc.authorscopusid55549046400
dc.authorscopusid26429877700
dc.authorscopusid15020075600
dc.authorscopusid36039473500
dc.contributor.authorCaglar, S.
dc.contributor.authorAdigüzel, E.
dc.contributor.authorSariboǧa, B.
dc.contributor.authorTemel, E.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T13:57:51Z
dc.date.available2020-06-21T13:57:51Z
dc.date.issued2014
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Caglar] Sema, Department of Chemistry, Erzincan Binali Yıldırım Üniversitesi, Erzincan, Turkey; [Adigüzel] Ekrem, Department of Chemistry, Erzincan Binali Yıldırım Üniversitesi, Erzincan, Turkey; [Sariboǧa] Bahtiyar, School of Health, Sinop Üniversitesi, Sinop, Turkey; [Temel] Ersin, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractMononuclear and dinuclear copper(II) complexes [Cu<inf>2</inf>(-nap) <inf>4</inf>(3-pic)<inf>2</inf>] (1) and [Cu(nap)<inf>2</inf>(H <inf>2</inf>O)(4-pic)<inf>2</inf>] (2) have been synthesized in the presence of 3-picoline and 4-picoline. Two complexes were characterized by FT-IR, UV-vis spectroscopic methods and their thermal stabilities were determined by TG/DTA/DTG techniques. The crystal structures of 1 and 2 were established by X-ray analysis. X-ray structure analysis has shown that copper(II) has a distorted square-pyramidal geometry. Naproxenate is a bridging ligand in 1 and monodentate in 2. Two complexes have shown catalytic activity on oxidation of 3,5-di-tert-butylcatechol to 3,5-di-tert-butylquinone exhibiting saturation kinetics at high substrate concentrations. The complexes were also screened for antimicrobial activity against pathogenic bacteria and fungi. The complexes exhibited antimicrobial activity against Entrococcus faecalis and Candida albicans. © 2014 Taylor & Francis.en_US
dc.identifier.doi10.1080/00958972.2014.891198
dc.identifier.endpage683en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-84899047985
dc.identifier.scopusqualityQ3
dc.identifier.startpage670en_US
dc.identifier.urihttps://doi.org/10.1080/00958972.2014.891198
dc.identifier.volume67en_US
dc.identifier.wosWOS:000333954500010
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltd.en_US
dc.relation.ispartofJournal of Coordination Chemistryen_US
dc.relation.journalJournal of Coordination Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAntimicrobial Activityen_US
dc.subjectCatechol Oxidationen_US
dc.subjectCopper(II) Complexen_US
dc.subjectNaproxenen_US
dc.titleMono- and Dinuclear Copper(II) Naproxenato Complexes Containing 3-Picoline and 4-Picoline: Synthesis, Structure, Properties, Catechol Oxidase, and Antimicrobial Activitiesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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