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Electrochemical and Spectroscopic Study of 4-(Phenyldiazenyl) (Hydroxymethyl)Methyl]Aminomethylene}Cyclohexa-3,5 Mechanism of the Azo and Imine Electroreduction

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dc.authorscopusid55774433600
dc.authorscopusid6603524165
dc.authorscopusid8328133400
dc.authorscopusid8723554800
dc.contributor.authorÇakir, S.
dc.contributor.authorBi̇Çer, E.
dc.contributor.authorOdaba̧soǧlu, M.
dc.contributor.authorAlbayrak, Ç.
dc.date.accessioned2020-06-21T15:36:47Z
dc.date.available2020-06-21T15:36:47Z
dc.date.issued2005
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Çakir] Semiha, Department of Chemistry, Gazi Üniversitesi, Ankara, Ankara, Turkey; [Bi̇Çer] Ender, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Odaba̧soǧlu] Mustafà, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Albayrak] Çĩgdem, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractNewly synthesized 4-(phenyldiazenyl)-2-{[tris(hydroxymethyl)methyl] aminomethylene} cyclohexa-3,5-dien-1(2H)-one was characterized by elemental analysis, FT-IR, NMR, electronic spectra, voltammetry. Tautomeric equilibrium of 4-(phenyldiazenyl)-2-{[tris(hydroxymethyl) methyl]aminomethylene}cyclohexa-3,5- dien-1(2H)-one in DMSO<inf>d</inf> is supported by 1H NMR data. The nature of electrochemical process of 4-(phenyldiazenyl)-2-{[tris(hydroxymethyl) methyl]aminomethylene}cyclohexa-3,5-dien-1(2H)-one in Britton-Robinson buffer (pH 2-9) was studied on the HMDE by square-wave (SWV), adsorptive stripping square-wave (AdSWV) and cyclic voltammetry (CV). The electrochemical parameters (I<inf>p</inf>/E<inf>p</inf>, I<inf>p</inf>/v<inf>p</inf>, I<inf>p</inf>/pH, I<inf>p</inf>/t<inf>acc</inf>) of the compound were determined. ©2005 Sociedade Brasileira de Química.en_US
dc.identifier.doi10.1590/S0103-50532005000500005
dc.identifier.endpage717en_US
dc.identifier.issn0103-5053
dc.identifier.issn1678-4790
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-24044453418
dc.identifier.scopusqualityQ3
dc.identifier.startpage711en_US
dc.identifier.urihttps://doi.org/10.1590/S0103-50532005000500005
dc.identifier.volume16en_US
dc.identifier.wosWOS:000231221400005
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherSociedade Brasileira de Quimicaen_US
dc.relation.ispartofJournal of the Brazilian Chemical Societyen_US
dc.relation.journalJournal of the Brazilian Chemical Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subject4-(Phenyldiazenyl)-2-{[Tris(Hydroxymethyl)Methyl]Aminomethylene} Cyclohexa-3,5-Dien-1(2H)-Oneen_US
dc.subjectElectronic Spectraen_US
dc.subjectFT-IRen_US
dc.subjectVoltammetryen_US
dc.titleElectrochemical and Spectroscopic Study of 4-(Phenyldiazenyl) (Hydroxymethyl)Methyl]Aminomethylene}Cyclohexa-3,5 Mechanism of the Azo and Imine Electroreductionen_US
dc.typeArticleen_US
dspace.entity.typePublication

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