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EPR Study of Cu2+ Ion Doped Orotato(Nicotinamid)cobalt Single Crystal

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dc.authorscopusid58560121700
dc.authorscopusid6603897211
dc.authorscopusid36039473500
dc.contributor.authorYıldırım, I.
dc.contributor.authorKarabulut, B.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T13:39:20Z
dc.date.available2020-06-21T13:39:20Z
dc.date.issued2016
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yıldırım] İlkay, Department of Radiotherapy, Biruni Üniversitesi, Istanbul, Turkey; [Karabulut] Bünyamin, Department of Computer Engineering, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractWe have studied the Cu2+ ion doped orotato(nicotinamid)cobalt(II) complex by using EPR spectroscopy and X-ray diffraction. The single crystal is triclinic with the space group P1. The unit cell dimensions of the crystal are a = 7.2785(4) Å, b = 10.2349(5) Å, c = 12.7372(6) Å, α = 69.297(4)°, β = 74.791(4)° and γ = 76.995(4)°, with Z = 2. We analyzed the EPR spectra of both single crystal and powder of the complex at room temperature. EPR analysis indicates the presence of only one Cu2+ site. We obtained the spin Hamiltonian parameters from the single crystal data for the complex. The spin Hamiltonian parameters are g<inf>x</inf> = 2.032, g<inf>y</inf> = 2.116, g<inf>z</inf> = 2.319, A<inf>x</inf> = 28 G, A<inf>y</inf> = 66 G, A<inf>z</inf> = 126 G. These data indicate that the symmetry of paramagnetic center is rhombic. We constructed the ground state wave function of the Cu2+ ion. © 2015 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.saa.2015.01.100
dc.identifier.endpage613en_US
dc.identifier.issn1386-1425
dc.identifier.pmid25704568
dc.identifier.scopus2-s2.0-84946488762
dc.identifier.scopusqualityQ1
dc.identifier.startpage608en_US
dc.identifier.urihttps://doi.org/10.1016/j.saa.2015.01.100
dc.identifier.volume152en_US
dc.identifier.wosWOS:000365367100076
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopyen_US
dc.relation.journalSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCu2+ Ionen_US
dc.subjectEPRen_US
dc.subjectFT-IRen_US
dc.subjectOrotateen_US
dc.subjectX-Rayen_US
dc.titleEPR Study of Cu2+ Ion Doped Orotato(Nicotinamid)cobalt Single Crystalen_US
dc.typeArticleen_US
dspace.entity.typePublication

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