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Synthesis, Spectroscopic Characterization, and Oxidative C-C Coupling in New Copper(II) Salicylaldiminates Containing Sterically Hindered Phenol

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dc.authorscopusid35567201700
dc.authorscopusid35555793900
dc.contributor.authorKasumov, V.T.
dc.contributor.authorKöksal, F.
dc.date.accessioned2025-12-11T02:07:48Z
dc.date.issued2001
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Kasumov] Veli Tarık, Department of Chemistry, Harran Üniversitesi, Sanliurfa, Turkey; [Köksal] Fevzi, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractNew bis[N-(2,6-di-tert-butyl-1-hydroxyphenyl)salicylideneminato]copper(II) complexes bearing HO and CH<inf>3</inf>O substituents on the salicyaldehyde moiety were prepared, and have been characterized by elemental analyses, IR, UV/Vis, ESR spectroscopy, and magnetic moments. It has been found that in the synthesis of CH<inf>3</inf>O substituted complexes unlike HO bearing, the oxidative C-C coupling of coordinated salicylaldimine ligands take place. It has been suggested that the intermolecular H-bonding is a dominant factor in controlling of oxidative C-C coupling conversion. The powder ESR spectra of CH<inf>3</inf>O substituted compounds unlike of HO are typical of a triplet state CuII dimers with a half-field forbidden (ΔM = ± 2) and the allowed (ΔM = ± 1) transitions at 300 and 113 K. © WILEY-VCH Verlag GmbH, D-69451 Weinheim, 2001.en_US
dc.identifier.doi10.1002/1521-3749(200111)627:11<2553
dc.identifier.endpage2558en_US
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-0035619496
dc.identifier.scopusqualityQ3
dc.identifier.startpage2553en_US
dc.identifier.urihttps://doi.org/10.1002/1521-3749(200111)627:11<2553
dc.identifier.urihttps://hdl.handle.net/20.500.12712/47680
dc.identifier.volume627en_US
dc.identifier.wosqualityN/A
dc.language.isoenen_US
dc.publisherWiley-VCH Verlagen_US
dc.relation.ispartofZeitschrift für Anorganische und Allgemeine Chemieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCopperen_US
dc.subjectESR Spectroscopyen_US
dc.subjectSalicylaldiminatesen_US
dc.subjectUV-Vis Spectroscopyen_US
dc.titleSynthesis, Spectroscopic Characterization, and Oxidative C-C Coupling in New Copper(II) Salicylaldiminates Containing Sterically Hindered Phenolen_US
dc.typeArticleen_US
dspace.entity.typePublication

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