Publication: Synthesis and Catalytic Activity of Novel Benzimidazolinylidene-Ruthenium(II) Complexes
| dc.contributor.author | Demir, Serpil | |
| dc.contributor.author | Ozdemir, Ismail | |
| dc.contributor.author | Sahin, Onur | |
| dc.contributor.author | Cetinkaya, Bekir | |
| dc.contributor.author | Büyükgüngör, Orhan | |
| dc.contributor.authorID | Sahin, Onur/0000-0003-3765-3235 | |
| dc.contributor.authorID | Cetinkaya, Bekir/0000-0002-4551-8650 | |
| dc.date.accessioned | 2020-06-21T14:52:45Z | |
| dc.date.available | 2020-06-21T14:52:45Z | |
| dc.date.issued | 2010 | |
| dc.department | OMÜ | en_US |
| dc.department-temp | [Demir, Serpil -- Ozdemir, Ismail] Inonu Univ, Fac Sci & Art, Dept Chem, TR-44280 Malatya, Turkey -- [Sahin, Onur -- Büyükgüngör, Orhan] Ondokuz Mayis Univ, Dept Phys, TR-55139 Kurupelit, Turkey -- [Cetinkaya, Bekir] Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey -- | en_US |
| dc.description.abstract | The reaction of [RuCl2(p-cymene)](2) with 1,3-dialkyl-benzimidazolium salts 1a-d in the presence of a small excess of cesium carbonate yields chelated eta(6)-arene, eta(1)-carbene ruthenium complexes 2a-d. All compounds were characterized by elemental analysis, NMR spectroscopy and the molecular structures of two of the complexes were determined by X-ray crystallography. The catalytic activity of RuCl2(eta(6)-arene, eta(1)-benzimidazolinylidene) complexes was evaluated in the direct arylation of 2-phenylpyridine with bromobenzene derivatives. | en_US |
| dc.description.sponsorship | TUBITAK-CNRS (France)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-U/181 (106T716)]; Inonu University Research FundInonu University [2009/13]; Faculty of Arts and Sciences, Ondokuz Mayiotas University, TurkeyOndokuz Mayis University [F279] | en_US |
| dc.description.sponsorship | This work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-CNRS (France) [TBAG-U/181 (106T716)], the Inonu University Research Fund (I.U. B. A. P: 2009/13) and the Faculty of Arts and Sciences, Ondokuz May iota s University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased from grant no. F279 of the University Research Fund). | en_US |
| dc.identifier.doi | 10.1055/s-0029-1219187 | |
| dc.identifier.endpage | 500 | en_US |
| dc.identifier.issn | 0936-5214 | |
| dc.identifier.issn | 1437-2096 | |
| dc.identifier.issue | 3 | en_US |
| dc.identifier.startpage | 496 | en_US |
| dc.identifier.uri | https://doi.org/10.1055/s-0029-1219187 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/18099 | |
| dc.identifier.wos | WOS:000274233900033 | |
| dc.language.iso | en | en_US |
| dc.publisher | Georg Thieme Verlag Kg | en_US |
| dc.relation.journal | Synlett | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Ruthenium | en_US |
| dc.subject | Benzimidazolinylidene Complexes | en_US |
| dc.subject | N-Heterocyclic Carbene | en_US |
| dc.subject | C-H Bond Activation | en_US |
| dc.subject | Arylation | en_US |
| dc.title | Synthesis and Catalytic Activity of Novel Benzimidazolinylidene-Ruthenium(II) Complexes | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |