Synthesis, Characterization, and Crystal Structure of Bis[4-(3′-benzoyl)thiocarbamidophenyl]Ether

Abstract

The title compound, bis[4-(3′-benzoyl)thiocarbamidophenyl]ether, was synthesized by the reaction of benzoylisothiocyanate with 4,4′-diaminodiphenylether in aprotic solvent. The structure was determinated by means of elemental analysis and FT-IR, 1H-NMR, 13C-NMR and MS spectroscopic techniques. The crystal structure was characterized by X-ray syngle crystal analysis: orthorhombic, sp. gr. Pnna, Z = 4. In crystal packing, there are intramolecular hydrogen bond N-H⋯O generating S(6) motif, and intermolecular hydrogen bond N-H⋯S forming R<inf>2</inf> 2 (8) ring. © 2014, Pleiades Publishing, Inc.