Publication:
Mixed Ligand Complexes of Coumarilic Acid/Nicotinamide With Transition Metal Complexes: Synthesis and Structural Investigation

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dc.authorscopusid8870164800
dc.authorscopusid55807911900
dc.authorscopusid8361848500
dc.authorscopusid36039473500
dc.contributor.authorKöse, D.A.
dc.contributor.authorÖztürk, B.
dc.contributor.authorSahin, O.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T13:57:58Z
dc.date.available2020-06-21T13:57:58Z
dc.date.issued2014
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Köse] Dursun Ali, Department of Chemistry, Hitit University, Corum, Corum, Turkey; [Öztürk] Banu, Department of Chemistry, Hitit University, Corum, Corum, Turkey; [Sahin] Onur, Scientific and Technological Research Application and Research Center, Sinop Üniversitesi, Sinop, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractCoumarilate-nicotinamide complexes of CoII and ZnII were synthesized and investigated by elemental analysis, magnetic susceptibility, solid state UV-Vis, direct injection probe mass spectra, FTIR spectra, thermoanalytic TG-DTG/DTA, and crystal X-ray diffraction methods. It was obtained that both complex structures contain 2 mol aqua ligands, 2 mol coumarilate (CCA-) and 2 mol nicotinamide (NA) ligands per formula unit. The CCA- and NA ligands were bonded to metal cations as monodentate through acidic oxygen and nitrogen of pyridine ring, respectively. Thermal decomposition of each complex starts with dehydration and continue removing of 1 mol NA ligand. The thermal dehydration of the complexes takes place in one or two steps. The decomposition mechanism and thermal stability of the investigated complexes are interpreted in terms of their structures. The final decomposition products are found to be metal oxides. © 2013 Akadémiai Kiadó, Budapest, Hungary.en_US
dc.identifier.doi10.1007/s10973-013-3415-6
dc.identifier.endpage1524en_US
dc.identifier.issn1388-6150
dc.identifier.issn1588-2926
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-84893705517
dc.identifier.scopusqualityQ1
dc.identifier.startpage1515en_US
dc.identifier.urihttps://doi.org/10.1007/s10973-013-3415-6
dc.identifier.volume115en_US
dc.identifier.wosWOS:000330729100060
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Thermal Analysis and Calorimetryen_US
dc.relation.journalJournal of Thermal Analysis and Calorimetryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBenzo[b]Furancarboxylic Aciden_US
dc.subjectCoumarilic Aciden_US
dc.subjectCoumarine Derivativesen_US
dc.subjectCrystal Structureen_US
dc.subjectMetal Complexesen_US
dc.subjectNicotinamideen_US
dc.titleMixed Ligand Complexes of Coumarilic Acid/Nicotinamide With Transition Metal Complexes: Synthesis and Structural Investigationen_US
dc.typeArticleen_US
dspace.entity.typePublication

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