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Bis(p-Nitrobenzoxasulfamato) Complexes of Cadmium(II) and Mercury(II) - Synthesis, Spectra, and X-Ray Crystal Structures

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dc.authorscopusid58717985000
dc.authorscopusid6602218261
dc.authorscopusid6603822664
dc.authorscopusid6701793097
dc.authorscopusid7801686683
dc.authorscopusid15033124400
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorYazIcIlar, T.K.
dc.contributor.authorAndaç, O.
dc.contributor.authorKütük, H.
dc.contributor.authorBekdemir, Y.
dc.contributor.authorHarrison, W.T.A.
dc.date.accessioned2025-12-11T02:10:24Z
dc.date.issued2002
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yilmaz] Veysel T., Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [YazIcIlar] Turan Kaya, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Andaç] Ömer, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Kütük] Halil, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Bekdemir] Yunus, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Harrison] William T.A., Department of Chemistry, University of Aberdeen, Aberdeen, Scotland, United Kingdomen_US
dc.description.abstractThe reaction of sodium benzoxasulfamate (nbs) with cadmium(II) and mercury(II) sulfate in aqueous solution yield the novel complexes [Cd(nbs)<inf>2</inf>(H<inf>2</inf>O)<inf>4</inf>] (1) and [Hg(nbs)<inf>2</inf>(H<inf>2</inf>O)<inf>3</inf>] (2), respectively. The complexes were characterized by elemental analyses, IR spectroscopy and X-ray crystallography. Complex 1 is monomeric and has an octahedral arrangement in which the N-donor nbs ligands occupy the axial positions, while the water oxygen atoms form the equatorial plane. Complex 2 is polymeric and shows a pentagonal bipyramidal arrangement achieved by the bridging of the HgN<inf>2</inf>O<inf>3</inf> units through the weak interaction of the O atoms of the nitro group. The nbs ligands also occupy the axial positions of the pentagonal bipyramid, whereas three water and two nitro oxygen atoms constitute the pentagonal plane. The crystal structure packing in both crystals is achieved by the intermolecular hydrogen bonds involving water hydrogen atoms, nitro and sulfonyl oxygen atoms.en_US
dc.identifier.doi10.1002/1521-3749(200208)628:8<1908
dc.identifier.endpage1912en_US
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-0036056982
dc.identifier.scopusqualityQ3
dc.identifier.startpage1908en_US
dc.identifier.urihttps://doi.org/10.1002/1521-3749(200208)628:8<1908
dc.identifier.urihttps://hdl.handle.net/20.500.12712/47741
dc.identifier.volume628en_US
dc.identifier.wosqualityN/A
dc.language.isoenen_US
dc.relation.ispartofZeitschrift für Anorganische und Allgemeine Chemieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCadmium(II)en_US
dc.subjectCrystal Structuresen_US
dc.subjectMercury(II)en_US
dc.subjectp-Nitrobenzoxasulfamateen_US
dc.titleBis(p-Nitrobenzoxasulfamato) Complexes of Cadmium(II) and Mercury(II) - Synthesis, Spectra, and X-Ray Crystal Structuresen_US
dc.typeArticleen_US
dspace.entity.typePublication

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