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Pyridine-2,5 Acid Complexes of Nickel(II) with 2,2́-Bipyridine and 1,10-Phenanthroline Coligands; Syntheses, Crystal Structures, Spectroscopic and Thermal Studies

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dc.authorscopusid16021063600
dc.authorscopusid26632875300
dc.authorscopusid16403949600
dc.authorscopusid36039473500
dc.contributor.authorÇolak, A.T.
dc.contributor.authorAkduman, D.
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T14:54:17Z
dc.date.available2020-06-21T14:54:17Z
dc.date.issued2009
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Çolak] Alper Tolga, Department of Chemistry, Dumlupinar Üniversitesi, Kutahya, Turkey; [Akduman] Demet, Department of Chemistry, Dumlupinar Üniversitesi, Kutahya, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractTwo pyridine-2,5-dicarboxylic acid (pydcH<inf>2</inf>) complexes of nickel(II) with 2,2́-bipyridine and 1,10-phenanthroline were synthesized and characterized by elemental, spectroscopic, thermal analysis, magnetic measurements and single crystal X-ray diffraction techniques. Both [Ni(pydc)(bipy)<inf>2</inf>]•7H<inf>2</inf>O and [Ni(pydc)(phen) <inf>2</inf>]•6.5H<inf>2</inf>O crystallize in the monoclinic system and P2<inf>1</inf>/c space group. The Ni(II) ions are coordinated by two bidentate bipy or phen ligands and one pydc dianion in a distorted octahedral geometry. The pydc ligand is coordinated through the pyridine nitrogen atom and oxygen atom of carboxyl group as a bidentate ligand. Both carboxylate groups of pydc are deprotonated but only the 2-carboxylate is coordinated to the metal. Thermal decompositions of the complexes have been studied over the range 30-600 °C on heating in a static air atmosphere. © 2009 Springer Science+Business Media B.V.en_US
dc.identifier.doi10.1007/s11243-009-9275-z
dc.identifier.endpage868en_US
dc.identifier.issn0340-4285
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-70749152682
dc.identifier.scopusqualityQ3
dc.identifier.startpage861en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-009-9275-z
dc.identifier.volume34en_US
dc.identifier.wosWOS:000271738900007
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistryen_US
dc.relation.journalTransition Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titlePyridine-2,5 Acid Complexes of Nickel(II) with 2,2́-Bipyridine and 1,10-Phenanthroline Coligands; Syntheses, Crystal Structures, Spectroscopic and Thermal Studiesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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