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1,3-Bis(2-Ethoxyphenyl)Imidazolidin-2-Ylidene]Bromo(Cycloocta-1,5-Diene)Rhodium(I)

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dc.authorscopusid56054780100
dc.authorscopusid8398877200
dc.authorscopusid11439933100
dc.authorscopusid7006471258
dc.authorscopusid36039473500
dc.contributor.authorDinçer, M.
dc.contributor.authorÖzdemir, Nutullah
dc.contributor.authorEmin Günay, M.E.
dc.contributor.authorÇetinkaya, B.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T15:30:53Z
dc.date.available2020-06-21T15:30:53Z
dc.date.issued2005
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Dinçer] Muharrem, Department of Physics, Arts and Sciences Faculty, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Özdemir] Namık, Department of Physics, Arts and Sciences Faculty, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Emin Günay] Muhammet, Faculty of Science and Arts, Aydin Adnan Menderes University, Aydin, Efeler, Turkey; [Çetinkaya] Bekir, Department of Chemistry, Ege Üniversitesi, Izmir, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Arts and Sciences Faculty, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractThe title complex, [RhBr(C<inf>8</inf>H<inf>12</inf>)(C<inf>19</inf>H <inf>22</inf>N<inf>2</inf>O<inf>2</inf>)], has a distorted square-planar geometry. There are two molecules, A and B, in the asymmetric unit. The Rh-C bond distance between the N-heterocyclic ligand and the metal atom is 2.039 (2) Å in molecule A and 2.042 (2) Å in molecule B. The angle between the carbene heterocycle and the coordination plane is 87.56 (12)° in molecule A and 87.03 (11)° in molecule B. It is shown that the average Rh-C(COD) (COD is cyclooctadiene) distance is linearly dependent on the Rh-C(imidazolidine) distance in this type of compound. This can be ascribed to the steric hindrance produced by the packing. The crystal structure contains intramolecular C-H⋯O and intermolecular C-H⋯Br interactions. © 2005 International Union of Crystallography.en_US
dc.identifier.doi10.1107/S0108270105013284
dc.identifier.endpagem375en_US
dc.identifier.issn0108-2701
dc.identifier.issn1600-5759
dc.identifier.issue8en_US
dc.identifier.pmid16082084
dc.identifier.scopus2-s2.0-30744475268
dc.identifier.startpagem373en_US
dc.identifier.urihttps://doi.org/10.1107/S0108270105013284
dc.identifier.volume61en_US
dc.identifier.wosWOS:000230987100002
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section C: Crystal Structure Communicationsen_US
dc.relation.journalActa Crystallographica Section C-Structural Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.title1,3-Bis(2-Ethoxyphenyl)Imidazolidin-2-Ylidene]Bromo(Cycloocta-1,5-Diene)Rhodium(I)en_US
dc.typeArticleen_US
dspace.entity.typePublication

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