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A Novel Two-Dimensional Silver(I) Saccharinato Coordination Polymer Constructed from Weak Ag⋯C Interactions: Synthesis, IR Spectra and X-Ray Structure

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dc.authorscopusid58717985000
dc.authorscopusid6603157555
dc.authorscopusid8600292400
dc.contributor.authorYilmaz, V.T.
dc.contributor.authorHamamci, S.
dc.contributor.authorKazak, C.
dc.date.accessioned2020-06-21T15:12:43Z
dc.date.available2020-06-21T15:12:43Z
dc.date.issued2008
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Yilmaz] Veysel T., Department of Chemistry, Bursa Uludağ Üniversitesi, Bursa, Bursa, Turkey; [Hamamci] Sevim, Department of Chemistry, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Kazak] Canan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractA new dinuclear silver(I)-saccharinato (sac) complex with acetonitrile (MeCN), [Ag<inf>2</inf>(sac)<inf>2</inf>(MeCN)<inf>2</inf>]<inf>n</inf> has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. The silver(I) ions are doubly bridged by two sac ligands, leading to a short argentophilic contact of 2.9074(3) Å. Each silver(I) ion exhibits a square-planar coordination geometry including the Ag-Ag bonds. The individual dimeric molecules are extended into a two-dimensional layered structure by weak Ag⋯C<inf>sac</inf> (η2) interactions of ca. 3.2 Å. These interactions were discussed and compared with those found in the first silver(I)-sac complex [Ag(sac)]<inf>n</inf>. © 2008 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.jorganchem.2008.09.053
dc.identifier.endpage3888en_US
dc.identifier.issue26en_US
dc.identifier.scopus2-s2.0-56349163759
dc.identifier.startpage3885en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2008.09.053
dc.identifier.volume693en_US
dc.identifier.wosWOS:000261162900014
dc.language.isoenen_US
dc.publisherElsevier Science SAen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.journalJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAg⋯Ag Interactionen_US
dc.subjectAg⋯C Interactionen_US
dc.subjectCoordination Polymeren_US
dc.subjectSaccharinateen_US
dc.subjectSquare-Planar Silver(I)en_US
dc.titleA Novel Two-Dimensional Silver(I) Saccharinato Coordination Polymer Constructed from Weak Ag⋯C Interactions: Synthesis, IR Spectra and X-Ray Structureen_US
dc.typeArticleen_US
dspace.entity.typePublication

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