| dc.contributor.author | Şahin O. | |
| dc.contributor.author | Büyükgüngör, Orhan | |
| dc.contributor.author | Köse D.A. | |
| dc.contributor.author | Zümreğlu-Karan B. | |
| dc.date.accessioned | 2020-06-21T09:24:44Z | |
| dc.date.available | 2020-06-21T09:24:44Z | |
| dc.date.issued | 2008 | |
| dc.identifier.issn | 1348-2238 | |
| dc.identifier.uri | https://doi.org/10.2116/analscix.24.x211 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/3862 | |
| dc.description.abstract | The title compound, tetraquaorotatonickel(II) monohydrate, C5H12N2O9Ni, crystallizes in the monoclinic space group P1 with the following unit-cell parameters: a = 7.2282(4)Å, b = 8.2959(4)Å, c = 10.0611(5)Å, ? = 80.115(4)°, ? = 70.479(4)°, ? = 65.779(4)° and Z = 2. The NiII ion is coordinated by a deprotonated N atom and the carboxylate O atom of the orotate ligand and four aqua ligands in a distorted octahedral geometry. Intermolecular N-H·O and O-H·O hydrogen bonds produce R22(8), R22(12), R22(16), R32(8), R43(8) and R44(12) rings, which lead to a one-dimensional polymeric chains. An extensive three-dimensional network of N-H···O and O-H···O hydrogen bonds, ?-? and N-H···? interactions are responsible for crystal stabilization. 2008 © The Japan Society for Analytical Chemistry. | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Japan Society for Analytical Chemistry | en_US |
| dc.relation.isversionof | 10.2116/analscix.24.x211 | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.title | Synthesis and crystal structure of tetraquaorotatonickel(II) monohydrate | en_US |
| dc.type | note | en_US |
| dc.contributor.department | OMÜ | en_US |
| dc.identifier.volume | 24 | en_US |
| dc.identifier.issue | 9 | en_US |
| dc.identifier.startpage | x211 | en_US |
| dc.identifier.endpage | x212 | en_US |
| dc.relation.journal | Analytical Sciences: X-ray Structure Analysis Online | en_US |
| dc.relation.publicationcategory | Diğer | en_US |
