| dc.contributor.author | Kutuk, H | |
| dc.contributor.author | Tillett, JG | |
| dc.date.accessioned | 2020-06-21T15:49:31Z | |
| dc.date.available | 2020-06-21T15:49:31Z | |
| dc.date.issued | 2001 | |
| dc.identifier.issn | 1042-6507 | |
| dc.identifier.uri | https://doi.org/10.1080/10426500108055106 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12712/22248 | |
| dc.description | WOS: 000173018400010 | en_US |
| dc.description.abstract | Second-order rate constants have been determined for the alkaline hydrolyses of N-aroyl-p-toluenesulfonimidic esters in aqueous organic solvents. Rate minima were observed with decreasing water concentration in aqueous acetonitrile, dioxane and t-butanol mixtures whereas rates of hydrolysis decrease continuously in MeOH-H2O and increase in DMSO-H2O. Solvent effects, Arrhenius parameters, and substituent effects are consistent with either an addition-elimination or a concerted S(N)2-type mechanism. | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Taylor & Francis Ltd | en_US |
| dc.relation.isversionof | 10.1080/10426500108055106 | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | alkaline hydrolysis | en_US |
| dc.subject | solvent effects | en_US |
| dc.subject | sulfonimidic esters | en_US |
| dc.title | Solvent effects on the alkaline hydrolyses of 4-nitrophenyl N-aroyl-areneiminosulfonates | en_US |
| dc.type | article | en_US |
| dc.contributor.department | OMÜ | en_US |
| dc.identifier.volume | 176 | en_US |
| dc.identifier.startpage | 95 | en_US |
| dc.identifier.endpage | 109 | en_US |
| dc.relation.journal | Phosphorus Sulfur and Silicon and the Related Elements | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
