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Kinetics and mechanisms of the acid-catalyzed hydrolyses of N-(4-Substitued-arylsulfinyl)phthalimides

dc.contributor.authorKutuk, H
dc.contributor.authorBekdemir, Y
dc.contributor.authorSoydas, Y
dc.date.accessioned2020-06-21T15:49:18Z
dc.date.available2020-06-21T15:49:18Z
dc.date.issued2001
dc.identifier.issn0894-3230
dc.identifier.urihttps://doi.org/10.1002/poc.353
dc.identifier.urihttps://hdl.handle.net/20.500.12712/22199
dc.descriptionWOS: 000167763800006en_US
dc.description.abstractThe acid-catalyzed hydrolyses of N-(4-substituted-arylsulfinyl)phthalimides were studied in aqueous solutions of perchloric and sulfuric acids at 50.0 +/- 0.1 and of hydrochloric acid at 40.0 +/- 0.1 degreesC. Analysis of the data by the Cox-Yates excess acidity method and substituent, temperature and solvent isotope effects indicate hydrolysis by an A2 mechanism at low acidity. At higher acidities a changeover to an Al mechanism is observed. Copyright (C) 2001 John Wiley & Sons, Ltd.en_US
dc.language.isoengen_US
dc.publisherJohn Wiley & Sons Ltden_US
dc.relation.isversionof10.1002/poc.353en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-(4-substituted-arylsulfinyl)phthalimidesen_US
dc.subjectexcess acidityen_US
dc.subjecthydrolysisen_US
dc.subjectacid catalysisen_US
dc.subjectmechanismen_US
dc.titleKinetics and mechanisms of the acid-catalyzed hydrolyses of N-(4-Substitued-arylsulfinyl)phthalimidesen_US
dc.typearticleen_US
dc.contributor.departmentOMÜen_US
dc.identifier.volume14en_US
dc.identifier.issue4en_US
dc.identifier.startpage224en_US
dc.identifier.endpage228en_US
dc.relation.journalJournal of Physical Organic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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