Bis(triethanolamine)cadmium(II) and -mercury(II) saccharinates: seven-coordinate complexes containing both tri- and tetradentate triethanolamine ligands
dc.contributor.author | Andac, O | |
dc.contributor.author | Topcu, Y | |
dc.contributor.author | Yılmaz, Veysel T. | |
dc.contributor.author | Guven, K | |
dc.date.accessioned | 2020-06-21T15:49:01Z | |
dc.date.available | 2020-06-21T15:49:01Z | |
dc.date.issued | 2001 | |
dc.identifier.issn | 0108-2701 | |
dc.identifier.uri | https://doi.org/10.1107/S0108270101015049 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/22120 | |
dc.description | Yilmaz, Veysel/0000-0002-2849-3332; TOPCU, YILDIRAY/0000-0002-2095-6603; Andac, Omer/0000-0003-3641-9690 | en_US |
dc.description | WOS: 000172548200007 | en_US |
dc.description | PubMed: 11740089 | en_US |
dc.description.abstract | The structures of the title triethanolamine (tea) complexes of Cd-II and Hg-II saccharinates, bis(triethanolamine)-kappa O-3,N,O'; kappa O-4,N,O',O " -cadmium(II) 1,2-benzisothiazol-3(2H)-onate 1,1-dioxide, [Cd(C6H15NO3)(2)](C7H4NO3S)(2), (I), and bis(triethanolamine)-kappa O-3,N,O'; kappa O-4,N,O',O " -mercury(II) 1,2-benzisothiazol-3(2H)-onate 1,1-dioxide, [Hg(C6H15NO3)(2)](C7H4NO3S)(2), (II), or [M(tea)(2)](sac)(2), where M is Cd-II or Hg-II and sac is the saccharinate anion, reveal seven-coordinate metal ions in both complexes. Both complex cations, [M(tea)(2)](2+), adopt a monocapped trigonal prism geometry in which the two tea ligands exhibit different coordination modes to achieve seven-coordination. One tea ligand acts as a tetradentate ligand using all its donor atoms, while the other behaves as a tridentate O,N,O'-donor ligand, with one of its ethanol groups remaining uncoordinated. The H atoms of the free and coordinated hydroxyl groups of the tea ligands are involved in hydrogen bonding with the amine N atom, and with the carbonyl and sulfonyl O atoms of neighbouring sac ions, forming an infinite three-dimensional network. A weak pi-pi interaction between the phenyl rings of the sac ions also occurs. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Munksgaard Int Publ Ltd | en_US |
dc.relation.isversionof | 10.1107/S0108270101015049 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.title | Bis(triethanolamine)cadmium(II) and -mercury(II) saccharinates: seven-coordinate complexes containing both tri- and tetradentate triethanolamine ligands | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 57 | en_US |
dc.identifier.startpage | 1381 | en_US |
dc.identifier.endpage | 1384 | en_US |
dc.relation.journal | Acta Crystallographica Section C-Crystal Structure Communications | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
Bu öğenin dosyaları:
Dosyalar | Boyut | Biçim | Göster |
---|---|---|---|
Bu öğe ile ilişkili dosya yok. |
Bu öğe aşağıdaki koleksiyon(lar)da görünmektedir.
-
PubMed İndeksli Yayınlar Koleksiyonu [6144]
PubMed Indexed Publications Collection -
Scopus İndeksli Yayınlar Koleksiyonu [14046]
Scopus Indexed Publications Collection -
WoS İndeksli Yayınlar Koleksiyonu [12971]
WoS Indexed Publications Collection