dc.contributor.author | Topcu, Y | |
dc.contributor.author | Andac, O | |
dc.contributor.author | Yılmaz, Veysel T. | |
dc.contributor.author | Harrison, WTA | |
dc.date.accessioned | 2020-06-21T15:45:43Z | |
dc.date.available | 2020-06-21T15:45:43Z | |
dc.date.issued | 2002 | |
dc.identifier.issn | 0095-8972 | |
dc.identifier.uri | https://doi.org/10.1080/0095897022000001557 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/22010 | |
dc.description | TOPCU, YILDIRAY/0000-0002-2095-6603; Andac, Omer/0000-0003-3641-9690; Yilmaz, Veysel/0000-0002-2849-3332 | en_US |
dc.description | WOS: 000177398000007 | en_US |
dc.description.abstract | The novel transition metal saccharinate complexes of triethanolamine (TEA) have been synthesized and characterized by elemental analyses, magnetic moments, LTV-Vis and IR spectra. Mn(II), Co(II), Ni(II), Zn(II), Cd(II) and Hg(II) form mononuclear complexes of [M(TEA)(2)](SAC)(2), where SAC is the saccharinate ion, while the Cu(II) complex is dimeric. The TEA ligand acts as a tridentate N,O,O'-donor ligand and one ethanol group is not involved in coordination. The SAC ion does not coordinate to the metal ions and is present as the counter-ion in the Mn(II), Co(II), Ni(II), Zn(II), Cd(II) and Hg(II) complexes, but coordinates to the Cu(II) ion as a monodentate ligand. The crystal structures of the [Co(TEA)(2)](SAC)(2) and [Cu-2(mu-TEA)(2)(SAC)(2)].2(CH3OH) complexes were determined by single crystal x-ray diffraction. The Co(II) ion has a distorted octahedral coordination by two TEA ligands. The Cu(II) complex crystallizes as a dimethanol solvate and has doubly alkoxo-bridged centrosymmetric dimeric molecules involving two tridentate triethanolaminate (deprotonated TEA) and two monodentate SAC ligands. The geometry of each Cu(II) ion is a distorted square pyramid. Both crystal structures are stabilized by hydrogen bonds to form a three-dimensional network. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Taylor & Francis Ltd | en_US |
dc.relation.isversionof | 10.1080/0095897022000001557 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | saccharin complexes | en_US |
dc.subject | triethanolamine complexes | en_US |
dc.subject | crystal structures | en_US |
dc.title | Synthesis, characterization and spectral studies of triethanolamine complexes of metal saccharinates. Crystal structures of [Co(TEA)(2)](SAC)(2) and [Cu-2(mu-TEA)2(SAC)(2)]center dot 2(CH3OH) | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 55 | en_US |
dc.identifier.issue | 7 | en_US |
dc.identifier.startpage | 805 | en_US |
dc.identifier.endpage | 815 | en_US |
dc.relation.journal | Journal of Coordination Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |