dc.contributor.author | Yılmaz, Veysel T. | |
dc.contributor.author | Hamamci, S | |
dc.contributor.author | Thone, C | |
dc.date.accessioned | 2020-06-21T15:44:15Z | |
dc.date.available | 2020-06-21T15:44:15Z | |
dc.date.issued | 2003 | |
dc.identifier.issn | 0095-8972 | |
dc.identifier.issn | 1029-0389 | |
dc.identifier.uri | https://doi.org/10.1080/0095897031000110664 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12712/21803 | |
dc.description | Yilmaz, Veysel/0000-0002-2849-3332; | en_US |
dc.description | WOS: 000184807900005 | en_US |
dc.description.abstract | The first 2-pyridylethanol (pyet) complexes of manganese(II), iron(II), cobalt(II), nickel(II), copper(II) and zinc(II) saccharinates, were synthesized and characterized by elemental analyses, magnetic measurements, UV-Vis, and IR spectroscopic techniques. Crystal and molecular structures of the iron(II) and copper(II) complexes were determined by single crystal X-ray diffractometry. The experimental data showed that all the complexes are mononuclear with a general formula [M(H2O)(2)(pyet)(2)](sac)(2), where sac is the saccharinate anion. All the metal ions are octahedrally coordinated by two aqua and two pyet ligands. The pyet ligand acts as a bidentate ligand through its amine nitrogen and hydroxyl oxygen atoms forming a six-membered chelate ring, while the sac ions remain outside the coordination sphere: All the complexes are isomorphous with a monoclinic space group P2(1)/n and Z=2. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Taylor & Francis Ltd | en_US |
dc.relation.isversionof | 10.1080/0095897031000110664 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 2-pyridylethanol complexes | en_US |
dc.subject | metal saccharinates | en_US |
dc.subject | crystal structures | en_US |
dc.title | Synthesis, special and structural characterization of the first Bis-2-pyridylethanol complex of Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II) saccharinates: Crystal structurs of diaquabis(2-pyridylethanol)iron(II) and copper(II) saccharinates | en_US |
dc.type | article | en_US |
dc.contributor.department | OMÜ | en_US |
dc.identifier.volume | 56 | en_US |
dc.identifier.issue | 9 | en_US |
dc.identifier.startpage | 787 | en_US |
dc.identifier.endpage | 795 | en_US |
dc.relation.journal | Journal of Coordination Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |