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Synthesis, spectra and crystal structure of 2-({[3-(methyl {3-[(2-hydroxybenzylidene)amino]propyl} amino)propyl]imino}methyl)phenol copper(II) complex

Date

2003

Author

Yılmaz, Veysel T.
Degirmencioglu, I
Andac, O
Karabocek, S
Slawin, AMZ

Metadata

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Abstract

A copper(II) complex, [Cu(salenN3], [salenN3H2 = 2-({[3-(methyl{3-[(2-hydroxybenzylidene)amino]propyl}amino)propyl]imino}methyl)phenol] was synthesized and characterized by elemental analyses, FTIR spectra and single crystal X-ray diffraction. The complex crystallizes in the monoclinic space group P21/c with a = 6.877(3), b = 14.109(6), c = 20.106(8) Angstrom, beta = 92.231(14), V = 1949.5(14) Angstrom(3). The salen ligand loses two phenolic hydrogens being a dianion and coordinates to the copper(II) ion as a pentadentate ligand through its two O and three N atoms. The copper(II) complex is five-coordinate, lying between perfect square pyramidal and trigonal-bipyramidal extremes. Use of the structural index parameter (tau) for five coordinate metal complexes indicated that the copper(II) complex exhibits a grater tendency toward trigonal-based-pyramidal geometry (tau > 0.5). The individual molecules in the crystal are held together by C-H(...)pi and (HH)-H-... interactions. The IR and electronic spectra of the complex were discussed in detail. (C) 2003 Elsevier Science B.V. All rights reserved.

Source

Journal of Molecular Structure

Volume

654

Issue

01.Mar

URI

https://doi.org/10.1016/S0022-2860(03)00205-9
https://hdl.handle.net/20.500.12712/21800

Collections

  • Scopus İndeksli Yayınlar Koleksiyonu [14046]
  • WoS İndeksli Yayınlar Koleksiyonu [12971]



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