[Hg-2(mu-bpe)(mu-OAc)(2)(mu-SCN)(2)], a new two-dimensional coordination polymer involving three simultaneously bridging ligands: 1,2-bis(4-pyridyle)ethene, acetate, and thiocyanate
Özet
A new mercury(II) complex of 1,2-bis(4-pyridyle)ethene (bpe) with anionic acetate and thiocyanate ligands has been synthesized and characterized by elemental analysis, IR, H-1 NMR and C-13 NMR spectroscopy. The single crystal X-ray analysis shows that the complex is a two-dimensional polymer with simultaneously bridging 1,2-bis(4-pyridyle)ethane, acetate and thiocyanate ligands and basic repeating dimeric [Hg-2(mu-bpe)(mu-OAc)(2)(mu-SCN)(2)] units. The two-dimensional system forms a three-dimensional network by packing via pi-pi stacking interactions.
