Bis(acesulfamato-kappa N-2(3),O-4)bis(2-aminopyrimidine-kappa N-1)copper(II)

Abstract

In the crystal structure of the title compound, bis(2-amino-pyrimidine-κ N-1)bis[6-methyl-1,2,3-oxathiazin-4(3H)-one 2,2-dioxide(1-)-κN-2(3),O-4]copper(II), [Cu(C4H4NO4S)(2)(C4H5N3)(2)], the first mixed-ligand complex of acesulfame, the Cull centre resides on a centre of symmetry and has an octahedral geometry that is distorted both by the presence of four-membered chelate rings and by the Jahn-Teller effect. The equatorial plane is formed by the N atoms of two aminopyrimidine (ampym) ligands and by the weakly basic carbonyl O atoms of the acesulfamate ligands, while the more basic deprotonated N atoms of these ligands are in the elongated axial positions with a strong misdirected valence. The crystal is stabilized by pyrimidine ring stacking and by intermolecular hydrogen bonding involving the NH2 Moiety Of the ampyrn ligand and the carbonyl O atom of the acesulfamate moiety.