Phenanthroline Cu(II)-bentonite composite characterization

Abstract

The penetration of the phenanthroline ligand into the interlayer space of the Cu-bentonite results in the formation of Cu(Phen)(3)-bentonite composite. The expansion of the d(001), basal spacing of the Cu-Bent from 14.24 to 17.7 angstrom on intercalation and the colour change indicate the cation immobilized dimeric ligand species' presence, which are thermally stable up to 315 degrees C. The shift to higher frequency of the ring vibrations resulted from the pi interactions is associated with the linkage of the tilted monomers to the smectite layers at elevated temperatures. The OH stretches and the bending peaks decrease in the intensity in parallel with an easy exchange between the water groups and the aromatic backboned ligands at room temperature.